2,4-Dimethylphenol 2,4-二甲基苯酚

CAS 105-67-9 MFCD00002233

化学结构图

105-67-9
SMILES:

化学属性

Mol. FormulaC8H10O
Mol. Weight122.16
Density1.011 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.538(lit.)
Boiling Point211-212 °C(lit.)
Vapor Pressure0.1 mmHg ( 25 °C)
Melting Point22-23 °C (lit.)
Flash Point96.11°C
TSCAYes
Solubility溶于水、醇。
Stability对光敏感

别名和识别编码

Chemical Name2,4-Dimethylphenol
CAS Number105-67-9
EC Number203-321-6
Beilstein Registry Number6,486
MDL NumberMFCD00002233
Synonym 2,4-DMP {LY} 2,4-DMP 2,4-Dimethylphenol 2,4-Xylenol 2,4-二甲基苯酚 2,4-二甲基苯酚 4-羟基间二甲苯 不对 2,4-二甲苯酚,间-4-二甲苯酚,4-羟基间二甲基苯,不对称间二甲苯酚, 1,3-二甲苯-4-酚,1-羟基-2,4-二甲苯,2,4-二甲基苯酚 2,4-二甲苯酚;间-4-二甲苯酚;4-羟基间二甲基苯;不对称间二甲苯酚;1,3-二甲苯-4-酚;1-羟基-2,4-二甲苯;2,4-二甲基苯酚 2,4-二甲酚, 1,3-二甲苯-4-酚,1-羟基-2,4-二甲苯,2,4-二甲基苯酚 4-二甲基苯酚 4-二甲苯 4-二甲苯酚 4-二甲酚标准溶液 4-羟基间二甲苯 4-羟基间二甲苯 不对称间二甲苯酚 ASYM-M-XYLENOL C8H10O (2,4-dimethyl-phenol) RCRA waste number U101 XYLENOL(2,4-) bacticin {} {LY} 2,4-DMP {} {} {LY} 2,4-DMP {} {} {} {LY} 2,4-DMP {} {} {} {} {LY} 2,4-DMP {} {} {} {} {} {LY} 2,4-DMP {} {} {} {} {} {} {LY} 2,4-DMP {} {} {} {} {} {} {} {LY} 2,4-DMP {} {} {} {} {} {} {} {} {LY} 2,4-DMP {} {} {} {} {} {} {} {} {} {LY} 2,4-DMP {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-DMP {} {} {} {} {} {} {} {}
PubChem Substance ID87567404
Merck Number10082
Chemical Name Translation2,4-二甲基苯酚
Reaxys-RN636244
Wiswesser Line NotationQR B1 D1
LabNetwork Molecule IDLN00194784
Canonical SMILESOC1=CC=C(C)C=C1C
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分类

  • {SNA} Alphabetical Listings, Flavors and Fragrances, Q-Z
  • {SNA} A-F, Alcoholic & Nonalcoholic Beverages, All Alphabetically Sorted, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical Standards for Flavors and Fragrances, Analytical/Chromatography, Chemical Class,

产品应用

  • 用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。

相关文献及参考

  • Short: II/27B
  • Merck:14,10082
  • Merck:14,10082 Beilstein:6,486
  • Short: III/35D2

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H303 May be harmfully swallowed 吞食可能有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSZE5600000
Packing GroupII
UN Number 3430 UN 2261 6.1/PG 2 UN2261
Hazard Codes T,N T,N,F
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1
Warnings 危化品目录(2015)
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 16 gm/kg/39W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   19,413,1959

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 183 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 18,868,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1040 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >30 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 23(10),52,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 18(2),58,1974

Restrict 危险品

其他信息

  • 用途三:用作防腐剂,用于有机合成。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
  • 毒性分级:中毒
  • Acros Organics:2,4-二甲基苯酚 2,4-Dimethylphenol, 99%(105-67-9)
  • 能与乙醇和乙醚混溶,微溶于水。有毒。有腐蚀性。
  • 急性毒性:口服-大鼠 LD50: 3200 毫克/公斤; 口服-小鼠 LD50: 809 毫克/公斤
  • Sigma Aldrich:105-67-9(sigmaaldrich)
  • 蒸气压:0.1 mm Hg ( 25 °C)
  • 用途二:用作防腐剂,并用于有机合成
  • TCI Shanghai:2,4-二甲基苯酚 2,4-Dimethylphenol,>;95.0%(GC)(105-67-9)
  • 可燃性危险特性:可燃; 燃烧产生有毒氯化物气体
  • 类别:有毒物品
  • MOL 文件:105-67-9.mol
  • 用途一:用于有机合成。
  • 上游原料:间二甲苯
  • Alfa Aesar:2,4-二甲基苯酚,98% 2,4-Dimethylphenol, 98%(105-67-9)
  • 酚类单一化合物标准液
  • 灭火剂:二氧化碳、砂土、泡沫、干粉
  • 外观性质:针状结晶。
  • 储运特性:库房通风低温干燥; 与食品原料、碱类、氧化剂分开储运
  • 图谱信息:2,4-二甲基苯酚(105-67-9)核磁图( 13 CNMR) 2,4-二甲基苯酚(105-67-9)红外图谱(IR1) 2,4-二甲基苯酚(105-67-9)质谱(MS)
  • 2,4-二甲基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010101 2,4-二甲苯酚 100g 80元 2011/04/16 D0774 2,4-二甲基苯酚 2,4-Dimethylphenol 25G 229元 2011/04/16 D0774 2,4-二甲基苯酚 2,4-Dimethylphenol 500G 971元
  • 方法一:由间二甲苯经磺化、盐析、碱熔、酸化而得。
  • 海关编码:29071400
  • MSDS 信息:2,4-二甲苯酚(105-67-9).msds

系列性分类


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