3-Bromobenzaldehyde, 97% 3-溴苯甲醛

CAS 3132-99-8 MFCD00003345

化学结构图

3132-99-8
SMILES: O=Cc1cccc(Br)c1

化学属性

Mol. FormulaC7H5BrO
Mol. Weight185.02
Boiling Point235.3°C at 760 mmHg
TSCAT
Density1.587
Refractive index1.5920 to 1.5950
Melting Point18-21°C
Flash Point96°C
Solubility分解
Stability对光敏感,对空气敏感
Appearance 1.5935，相对密度 1.5870，不溶于水，溶于苯、四氯化碳等溶剂。 本品为无色液体，b.p.228～230℃，n D 20
pH:A

别名和识别编码

Chemical Name3-Bromobenzaldehyde, 97%
CAS Number3132-99-8
Alfabeta NameBROMOBENZALDEHYDE 3-
MDL NumberMFCD00003345
Synonym 3-Bromobenzaldehyde {LY} 3-Bromobenzaldehyde {} {LY} 3-Bromobenzaldehyde {} {} {LY} 3-Bromobenzaldehyde {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromobenz
EC Number221-526-9
Beilstein Registry Number7,238
PubChem Substance ID76583
Chemical Name Translation3-溴苯甲醛
Reaxys-RN1634534
LabNetwork Molecule IDLN00007991
InChIInChI=1S/C7H5BrO/c8-7-3-1-2-6(4-7)5-9/h1-5H
Canonical SMILESO=CC1=CC=CC(Br)=C1
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分类

  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 拟除虫菊酯类杀虫剂
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; aldehyde; 1fragment
  • {SNA} Aldehydes, Building Blocks, C7, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Beilstein:7,238
  • Short: III/35D2
  • Short: III/35E

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P332+P313
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSCU4820000
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro
Hazard Codes Xn Xn,Xi
Packing GroupIII
Hazard Class6.1(b)
UN Number 2810 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534390

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1126 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - chromodacryorrhea
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534389

其他信息

  • 方法一:其制备方法是在苯甲醛的二氯乙烷溶液中，加入AlCl 3 为催化剂，再慢慢滴加含有溴的二氯乙烷溶液，加完后再反应一段时间进行后处理，蒸馏得到间溴苯甲醛。
  • 间溴苯甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 L0631301 3-溴苯甲醛97％ 25g 321元 2011/04/16 B0548 3-溴苯甲醛 3-Bromobenzaldehyde 500G 3080元 2011/04/16 B0548 3-溴苯甲醛 3-Bromobenzaldehyde 25G 366元
  • F:10
  • 用途一:用作医药中间体
  • 敏感性:Air Sensitive
  • TSCA:T
  • 下游产品:间苯氧基苯甲醛 --> 3-苯基苯甲基胺 --> 3-吗啉基苯甲醛 --> 3-溴苯甲醇
  • 海关编码:29130000
  • 图谱信息:间溴苯甲醛(3132-99-8)Raman光谱 间溴苯甲醛(3132-99-8)核磁图( 13 CNMR) 间溴苯甲醛(3132-99-8)质谱(MS) 间溴苯甲醛(3132-99-8)红外图谱(IR1) 间溴苯甲醛(3132-99-8)红外图谱(IR2)
  • Hazard Note:Irritant
  • 水中分解。
  • MSDS 信息:3-Bromobenzaldehyde(3132-99-8).msds
  • Alfa Aesar:3-溴苯甲醛,97% 3-Bromobenzaldehyde, 97%(3132-99-8)
  • MOL 文件:3132-99-8.mol
  • Sigma Aldrich:3132-99-8(sigmaaldrich)
  • color:very faintly to deep brownish-yellow
  • 用途二:间溴苯甲醛是制备间苯氧基苯甲醛的中间体，可以合成多种拟除虫菊酯。
  • TCI Shanghai:3-溴苯甲醛 3-Bromobenzaldehyde,>;98.0%(GC)(T)(3132-99-8)
  • Acros Organics:3-溴苯甲醛 3-Bromobenzaldehyde, 96%(3132-99-8)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes - Carbonyl Compounds
  6. C7 - Aldehydes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic aldehyde<including acetal,hemiacetal>
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes
  6. C10 to C21

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