Acenaphthenequinone 苊醌

CAS 82-86-0 MFCD00003805

化学结构图

82-86-0
SMILES: O=c1c(=O)c2cccc3cccc1c32

化学属性

Mol. FormulaC12H6O2
Mol. Weight182.18
Melting Point257-263
Density1.424
TSCAYes
Solubility不溶
Appearance 黄色针状结晶。熔点261℃（升华）。溶于醇、热苯、热甲苯，不溶于水。

别名和识别编码

Chemical NameAcenaphthenequinone
MDL NumberMFCD00003805
PubChem Substance ID87561710
Beilstein Registry Number879172
CAS Number82-86-0
EC Number201-441-3
Synonym 1,2-ACENAPHTHYLENEDIONE 1,2-Acenaphthenedione 1,2-Acenaphthylenedione 1,2-Acenaphthylenedione; 1,2-Diketoacenaphthene 1,2-DIHYDROACENAPHTHYLENEQUINONE 1,2-DIOXOACENAPHTHENE 1,2-diketoacenaphthene ACENAPHTHENEQUINONE ACENAPHTHEQUINONE ACENAPHTHOQUINONE ACENAPHTHYLENE-1,2-DIONE AKOS 92207 Acenaphth Acenaphthaquinone Acenaphthenequinone Acenaphthoquinone Acenaphthylene-1,2-quinone Acenaphthylenequinone NAPHTHYLENEETHYLENEQUINONE acenaphthene-1,2-dione acenaphthylene-1,2-quinone acenaphthylenequinone 乙烷合萘醌 二氢苊醌 二氧化苊 苊醌, 95% 萘喹啉 萘并乙二酮 萘并乙二酮,萘嵌戊二酮,二氧化苊
Reaxys-RN879172
Chemical Name Translation苊醌
LabNetwork Molecule IDLN00223608
InChIInChI=1S/C12H6O2/c13-11-8-5-1-3-7-4-2-6-9(10(7)8)12(11)14/h1-6H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; 10ring; 11ring; ketone; 1fragment
  • {SNA} Building Blocks, C11 to C12, Carbonyl Compounds, Cell Biology, Cell Signaling and Neuroscience, Chemical Synthesis, Cyclic Nucleotide Metabolism, G Proteins and Cyclic Nucleotides, Guanylyl Cyclase Inhibitors, Ketones, Organic Building Blocks
  • {SNA} A-AM, Bioactive Small Molecule Alphabetical Index, Building Blocks, C11 to C12, Carbonyl Compounds, Chemical Synthesis, Cyclic Nucleotide Metabolism, G Proteins and Cyclic Nucleotides, Guanylyl Cyclase Inhibitors, Ketones, Organic Building Blocks, 生物活性小分子,

产品应用

  • 苊醌是染料和杀虫剂的中间体。

相关文献及参考

  • Starting material for a three-step synthesis of corannulene: J. Am. Chem. Soc., 119, 10963 (1997), and also of a new C32H12 bowl-shaped aromatic hydrocarbon: Tetrahedron Lett., 38, 741 (1997).
  • Short: IV/1a
  • Short: III/5a
  • Short: EINECS
  • Beilstein:7(3)3796

安全信息

RTECSAB1024500
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 728 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 41,146,1978

其他信息

  • 可燃性危险特性:可燃;加热分解释放刺激烟雾
  • 储运特性:库房通风低温干燥
  • 毒性分级:中毒
  • 用途一:苊醌是染料和杀虫剂的中间体。
  • MSDS 信息:Acenaphthenequinone(82-86-0).msds
  • TCI Shanghai:苊醌 Acenaphthenequinone,>;95.0%(GC)(82-86-0)
  • 图谱信息:苊醌(82-86-0)质谱(MS) 苊醌(82-86-0)核磁图( 1 HNMR) 苊醌(82-86-0)红外图谱(IR1) 苊醌(82-86-0)核磁图( 13 CNMR) 苊醌(82-86-0)红外图谱(IR2)
  • 溶于醇；热苯；热甲苯，不溶于水。
  • Sigma Aldrich:82-86-0(sigmaaldrich)
  • 上游原料:亚硫酸氢钠 --> 重铬酸钠 --> 硅藻土 --> 邻二氯苯 --> 刚果红试纸 --> 苊 --> 重铬酸
  • 灭火剂:干粉、泡沫、砂土和水
  • 急性毒性:未明-大鼠LD50:728毫克/公斤
  • Acros Organics:苊醌 Acenaphthenequinone, 95%(82-86-0)
  • 方法一:由苊用重铬酸钠氧化而得：在带冷却夹套的不锈钢反应器内，投入苊、冰醋酸和乙酸高铈，搅拌，在2h内加入计量的二水合重铬酸钠，温度保持在40℃。然后在室温继续搅拌8h。加冷水稀释，过滤，用水洗涤至无酸性。将固体与10%碳酸钠溶液在蒸汽浴上煮30min，过滤，洗涤。再将固体用亚硫酸氢钠（4%溶液）在80℃提取30min，然后加入助滤硅藻土及活性炭，再过滤。重复提取一次，将滤液合并后在80℃和不断搅拌下用浓盐酸酸化至刚果红试纸变蓝色，继续在80℃保温搅拌1h。苊醌呈鲜黄色结晶析出，过滤，用水洗除酸性，得苊醌，产率38%-60%。熔点256-260℃。用邻二氯苯重结晶，结晶用甲醇冲洗后，熔点可达256-260℃。配料实例：苊100g，冰醋酸800ml，乙酸高铈5g，二水合重铬酸钠325g，得产品45-70g。
  • Alfa Aesar:苊醌,95% Acenaphthenequinone, 95%(82-86-0)
  • MOL 文件:82-86-0.mol
  • 海关编码:29146990
  • 苊醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K0004001 苊醌;萘并乙二酮;萘嵌戊二酮 100g 2011元 2011/04/16 A0004 苊醌 Acenaphthenequinone 25G 524元 2010/06/21 102191000 苊醌 Acenaphthenequinone 95% 100 GR 1602元
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C11 to C12 - Ketones
  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Cell Signaling and Neuroscience - Cell Biology
  4. G Proteins and Cyclic Nucleotides - Cell Signaling and Neuroscience
  5. Cyclic Nucleotide Metabolism - G Proteins and Cyclic Nucleotides
  6. Guanylyl Cyclase Inhibitors - Cyclic Nucleotide Metabolism
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C10
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. Ion Channels
  5. Ligand-Gated Ion Channels
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. G Proteins and Cyclic Nucleotides
  5. Cyclic Nucleotide Metabolism
  6. Cyclic Nucleotides and Analogs

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