(R)-1-(1-isocyanatoethyl)naphthalene (R)-1-(1-异氰酸酯乙基)萘

CAS 42340-98-7 MFCD00004015

化学结构图

42340-98-7
SMILES: C[C@@H](N=C=O)C1C=CC=C2C=CC=CC2=1

化学属性

Mol. FormulaC13H11NO
Mol. Weight197
Refractive index1.6050 to 1.6090
Boiling Point106-108 °C/0.16 mmHg(lit.)
Density1.118 g/mL at 25 °C(lit.)
Flash Point93°C(lit.)
TSCANo

别名和识别编码

Chemical Name(R)-1-(1-isocyanatoethyl)naphthalene
Synonym (R)-(-)-1-(1-萘基)乙基异氰酸酯 (R)-NEI
CAS Number42340-98-7
PubChem Substance ID87571691
EC Number255-759-2
Beilstein Registry Number4181805
MDL NumberMFCD00004015
Reaxys-RN4181805
Chemical Name Translation(R)-1-(1-异氰酸酯乙基)萘
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Isocyanates, Organic Building Blocks
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents,

相关文献及参考

  • Chiral derivatizing agent for separation of alcohols, amines and thiols by chromatography: J. Org. Chem., 39, 3904 (1974).
  • Chiral derivatizing agent for separation of alcohols, amines and thiols by chromatography: J. Org. Chem., 39, 3904 (1974).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P302+P352+P333+P313+P362+P364
  • P342+P311
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P337+P313
  • P403+P233
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P305+P351+P338+P337+P313
  • P301+P310+P330
  • P405 Store locked up. 上锁保管。
  • P304+P340+P311
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P305+P351+P338+P337
Signal word Danger {} {} {} {} {} {} {} {} {} {} {} {} {TCI}
UN Number 2206 UN2206
Storage condition Moisture Sensitive 0-10 0-10°C
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42/43
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R42 May cause sensitisation by inhalation 吸入会产生过敏反应
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Packing GroupIII
Hazard Class6.1

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Chiral Derivatization Reagents - Derivatization Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents HPLC - Derivatization Reagents
  5. Chiral - Derivatization Reagents HPLC
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Isocyanates - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Optical Resolution
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Functional Group 官能团索引
  2. isocyanate

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