Cycloocteneoxide 1,2-环氧环辛烷

CAS 286-62-4 MFCD00005164

化学结构图

286-62-4
SMILES: C1CCCC2OC2CC1

化学属性

Mol. FormulaC8H14O
Mol. Weight126.20
Boiling Point55 °C at 5 mmHg
Melting Point53-56 °C
Flash Point133 °F

别名和识别编码

Chemical NameCycloocteneoxide
Synonym 9-Oxabicyclo[6.1.0]Nonane {LY} 9-Oxabicyclo[6.1.0]Nonane {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Oxabicyclo[6.1.0]Nonane {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00005164
CAS Number286-62-4
EC Number206-010-3
Beilstein Registry Number17(5)1,234
PubChem Substance ID87569765
Reaxys-RN103543
Chemical Name Translation1,2-环氧环辛烷
InChIKeyMELPJGOMEMRMPL-UHFFFAOYSA-N
LabNetwork Molecule IDLN01742239
InChIInChI=1S/C8H14O/c1-2-4-6-8-7(9-8)5-3-1/h7-8H,1-6H2
Canonical SMILESC1CCCC2C(CC1)O2
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Epoxides, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; alicycle; large ring; fused rings; 3ring; 8ring; 9ring; ether; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Hazard Codes F,Xn Xn
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition 0-10 0-10°C 2-8°C
UN Number 1325 UN 1325 4.1/PG 3
Packing GroupIII
Hazard Class4.1

其他信息

  • 上游原料:乙醚 --> 硫酸镁 --> 无水醋酸钠 --> 过氧乙酸 --> 环辛烯
  • TCI Shanghai:1,2-环氧环辛烷 1,2-Epoxycyclooctane,>;97.0%(GC)(286-62-4)
  • Alfa Aesar:Cyclooctene oxide, 99%(286-62-4)
  • F:10-21
  • Sigma Aldrich:286-62-4(sigmaaldrich)
  • 1,2-环氧环辛烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0516 1,2-环氧环辛烷 1,2-Epoxycyclooctane 5G 530元 2014/06/02 E0516 1,2-环氧环辛烷 1,2-Epoxycyclooctane 25G 1580元 2010/06/21 111450250 1,2-环氧环辛烷 Cyclooctene oxide 99% 25 GR 1562元
  • 1,2-环氧环辛烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 E0516 1,2-环氧环辛烷 1,2-Epoxycyclooctane 5G 437元 2011/04/16 E0516 1,2-环氧环辛烷 1,2-Epoxycyclooctane 25G 1300元 2010/06/21 111450250 1,2-环氧环辛烷 Cyclooctene oxide 99% 25 GR 1562元
  • MOL 文件:286-62-4.mol
  • Acros Organics:1,2-环氧环辛烷 Cyclooctene oxide, 99%(286-62-4)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds

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