Dihydro-3-methylene-2(3H)-furanone 二氢-3-甲基-2(3H)-呋喃酮

CAS 547-65-9 MFCD00005407

化学结构图

547-65-9
SMILES: C=C1CCOC1=O

化学属性

Mol. FormulaC5H6O2
Mol. Weight98.10
Density1.119
Refractive index1.4710 to 1.4750
Boiling Point90°C/13mmHg(lit.)
Flash Point90°C(lit.)

别名和识别编码

Chemical NameDihydro-3-methylene-2(3H)-furanone
CAS Number547-65-9
EC Number208-931-6
Beilstein Registry Number107939
MDL NumberMFCD00005407
Synonym 3-METHYLENEDIHYDRO-2(3H)-FURANONE 二氢-3-亚甲基-2(3H)-呋喃酮 ALPHA-METHYLENE-GAMMA-BUTYROLACTONE A-亚甲基-G-丁内酯 2-甲烯基丁内酯;二氢-3-亚甲基-2(3H)-呋喃酮 DIHYDRO-3-METHYLENE-2(3H)-FURANONE alpha-Methylene butyrolactone alpha-Methylene-gamma-butyrolactone, stabilized, 95% α-methylene-γ-butyrolactone α-亚甲基-γ-丁内酯 Tetrahydro-3-methylene-2-furanone 3-methylideneoxolan-2-one 2-甲烯基丁内酯 Tulipane alpha-Methylene-gamma-butyrolactone
PubChem Substance ID87572894
Chemical Name Translation二氢-3-甲基-2(3H)-呋喃酮
Reaxys-RN107939
Merck Number6062
LabNetwork Molecule IDLN00221468
InChIInChI=1S/C5H6O2/c1-4-2-3-7-5(4)6/h1-3H2
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Lactones, Organic Building Blocks

相关文献及参考

  • [2]. McCluskey J, et al. Tulipalin A induced phytotoxicity.Int J Crit Illn Inj Sci. 2014 Apr;4(2):181-3.
  • Merck:6062
  • Merck:6062 Beilstein: 17,V,9,127
  • [1]. Zwicker P, et al.A proteomic approach for the identification of immunotoxic properties of Tulipalin A.Proteomics. 2016 Dec;16(23):2997-3008.
  • [1]. Zwicker P, et al.A proteomic approach for the identification of immunotoxic properties of Tulipalin A.Proteomics. 2016 Dec;16(23):2997-3008.
  • [2]. McCluskey J, et al. Tulipalin A induced phytotoxicity.Int J Crit Illn Inj Sci. 2014 Apr;4(2):181-3.

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
  • P302+P352+P333+P313+P362+P364
  • P304+P340+P342+P311
  • P304+P341
  • P305+P351+P338+P337+P313
  • P342+P311
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H227 Combustible liquid 可燃液体
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
Packing GroupIII
RTECSLU3580400
UN Number
Storage condition 0-10 0-10°C 2-8°C 储存温度2-8℃
Hazard Class3.2

其他信息

  • F:1-8-10
  • Acros Organics:a-亚甲基-g-丁内酯 alpha-Methylene-gamma-butyrolactone, stabilized, 95%(547-65-9)
  • TCI Shanghai:α-亚甲基-γ-丁内酯(含稳定剂2,6-二叔丁基对甲酚) alpha-Methylene-gamma-butyrolactone (stabilized with 2,6-Di-tert-butyl-p-cresol),>;95.0%(GC)(547-65-9)
  • 2-甲烯基丁内酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0907 α-亚甲基-γ-丁内酯(含稳定剂2,6-二叔丁基对甲酚) alpha-Methylene-gamma-butyrolactone (stabilized with 2,6-Di-tert-butyl-p-cresol) 25G 3870元 2014/06/02 M0907 α-亚甲基-γ-丁内酯(含稳定剂2,6-二叔丁基对甲酚) alpha-Methylene-gamma-butyrolactone (stabilized with 2,6-Di-tert-butyl-p-cresol) 1G 403元 2014/06/02 M0907 α-亚甲基-γ-丁内酯(含稳定剂2,6-二叔丁基对甲酚) alpha-Methylene-gamma-butyrolactone (stabilized with 2,6-Di-tert-butyl-p-cresol) 5G 1290元
  • MOL 文件:547-65-9.mol
  • MSDS 信息:3-Methylenedihydro-2(3H)-furanone(547-65-9).msds
  • Sigma Aldrich:547-65-9(sigmaaldrich)
  • 图谱信息:2-甲烯基丁内酯(547-65-9)红外图谱(IR1) 2-甲烯基丁内酯(547-65-9)质谱(MS) 2-甲烯基丁内酯(547-65-9)核磁图( 1 HNMR) 2-甲烯基丁内酯(547-65-9)Raman光谱 2-甲烯基丁内酯(547-65-9)核磁图( 13 CNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Lactones - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Lactones - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Lactams
  1. Medical Research Areas
  2. Metabolism
  3. Drug Metabolite  (药物代谢物)

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