Sodium dichloroisocyanurate 二氯异氰尿酸钠

CAS 2893-78-9 MFCD00006036

化学结构图

2893-78-9
SMILES: O=c1nc([O-])n(Cl)c(=O)n1Cl.[Na+]

化学属性

Mol. FormulaC3HCl2N3NaO3
Mol. Weight220.95
Density1.422
Melting Point225 °C
TSCAYes
Solubility30G/100ML (25 ºC)

别名和识别编码

Chemical NameSodium dichloroisocyanurate
Synonym Sodium dichloroisocyanurate {LY} Sodium dichloroisocyanurate {} {LY} Sodium dichloroisocyanurate {} {} {LY} Sodium dichloroisocyanurate {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium dichloroisocyanurate {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00006036
CAS Number2893-78-9
EC Number220-767-7
Beilstein Registry Number4056155
Reaxys-RN4056155
PubChem Substance ID517121
Chemical Name Translation二氯异氰尿酸钠
Wiswesser Line NotationT6MVNVNVJ CG GG &-NA-
InChIInChI=1S/C3HCl2N3O3.Na/c4-7-1(9)6-2(10)8(5)3(7)11;/h(H,6,9,10);/q;+1/p-1
Canonical SMILESO=C(N(Cl)C(N1)=O)N(Cl)C1=O.[Na]
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分类

  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; urea; 2fragments; ionic

相关文献及参考

  • Short: EINECS
  • Short: III/31a
  • Reagent for N-chlorination of primary and secondary amines, particularly useful for chlorination of hindered amines: Synth. Commun., 18, 2135 (1988).

安全信息

Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S41 In case of fire and/or explosion do not breathe fumes 着火和/或爆炸时,不要吸入烟雾;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S8 Keep container dry 保持容器干燥;
Risk Statements
  • R2 Risk of explosion by shock, friction, fire or other sources of ignition 遇到震动、摩擦、火焰或者其它引燃物有爆炸危险
  • R22 Harmful if swallowed 吞咽有害
  • R31 Contact with acids liberates toxic gas 与酸接触释放出有毒气体
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50/53
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施,避免与可燃物混合/...
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P308+P316
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSXZ1900000
Packing GroupII
UN Number 2465
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Moisture Sensitive Store at room temperature {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes 5.1 O,Xn,N O;Xn;N
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Class5.1
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3160 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - pulmonary emboli
   Liver - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555174

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 3570 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - ulceration or bleeding from stomach
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academ

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2500 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - coma
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   MONS** Monsanto Co. Toxicity Information.  (Monsanto Industrial Chemicals
   Co., Bancroft Bldg., Suite 204, 3411 Silverside Rd., Wilmington, DE 19810)
   Volume(issue)/page/year: -,-,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1420 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Liver - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555174

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 4 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
   Reproductive - Effects on Newborn - physical
REFERENCE :
   YKRYAH Yakubutsu Ryoho.  Medicinal Treatment.  (Tokyo, Japan)  V.1-14,
   1968-81.  Suspended.  Volume(issue)/page/year: 13,353,1980

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 4 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
   Reproductive - Effects on Newborn - physical
REFERENCE :
   YKRYAH Yakubutsu Ryoho.  Medicinal Treatment.  (Tokyo, Japan)  V.1-14,
   1968-81.  Suspended.  Volume(issue)/page/year: 13,23,1980

其他信息

  • 稳定性:Stable. Oxidizing agent - contact with combustible material may lead to fire. Incompatible with strong bases, strong oxidizing agents(??) Reacts
  • RTECS号:XZ1900000
  • MOL 文件:2893-78-9.mol
  • 生产方法:由氰尿酸经氯化而得。
  • 敏感性:Moisture Sensitive
  • HazardClass:5.1
  • EPA化学物质信息:1,3,5-Triazine-2, 4,6(1H,3H,5H)-trione, 1,3-dichloro-, sodium salt(2893-78-9)
  • 含氯消毒剂:二氯异氰尿酸钠与漂白粉、三合二、次氯酸钠是我国目前常用的几种含氯消毒剂,含氯消毒剂的消毒能力主要取决于其中所含的有效氯的含量,有效氯的含量越高,消毒能力越强。含氯消毒剂溶于水中形成次氯酸,由之产生杀菌作用。漂白粉与三合二在溶液中形成次氯酸的多少与pH有关,pH越低,次氯酸形成越多。二氯异氰尿酸钠水解常数较高,杀菌能力较大多数其他氯胺类消毒剂为强。与次氯酸盐类消毒剂相比,在低浓度下,二氯异氰尿酸钠作用较慢;在高浓度下,因其溶液可保持弱酸性,所以杀菌效果有时甚至可优于次氯酸盐类。上述含氯消毒剂杀菌谱广,对细菌繁殖体、病毒、真菌孢子及细菌芽孢都有杀灭作用。 二氯异氰尿酸钠又名优氯净,是氯化异氰尿酸类消毒药之一,同类品种还有氯溴异氰酸、三氯异氰尿酸、二氯异氰尿酸、二氯异氰尿酸钾等。本品及其他氯化异氰尿酸类消毒药杀菌谱较广,对细菌繁殖体、病毒、真菌孢子及细菌芽孢等均有较强的杀灭作用。对各种细菌(如大肠埃希杆菌、金黄色葡萄球菌等)、病毒(如肝炎病毒)、细菌芽孢(如枯草杆菌黑色变种芽孢)及真菌等均有较强的杀灭作用。在有效浓度的作用下,30分钟可杀灭大肠杆菌99.9%以上,5~30分钟可杀灭全部细菌芽孢,5分钟可杀灭全部肝炎病毒。本品还具有破坏乙肝表面抗原的作用。二氯异氰尿酸钠在酸性环境下作用增强,pH越低,作用越强。本品稳定性好,无致癌作用。可用于水、食品厂的加工器具及餐具、食品、车辆、畜禽舍、蚕室、鱼塘、用具等的消毒。
  • PackingGroup:II
  • 二氯异氰尿酸钠价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 LB2350403 二氯异氰尿酸钠,二水 97% (dry wt.), water<3% 500g 386元 2011/08/23 K3591502 二氯异三聚氰酸钠盐 250g 507元 2011/08/23 L1597203 二氯异氰酸钠 500g 465元
  • 毒害物质数据:2893-78-9(Hazardous Substances Data)
  • 外观性质:白色晶体,有氯气味。
  • 用途:用作消毒剂,可用于游泳池,饮用水消毒,预防性消毒及各种场所的环境消毒。可用于养蚕、家畜、家禽、鱼类饲养消毒。还可用于羊毛防缩整理、纺织工业漂白、工业循环水除藻、橡胶氯化剂,本产品高效、性能稳定,对人体无不良影响.
  • 理化性质:白色结晶性粉末,有浓厚的氯气味,含有效氯60%~64.5%。性稳定,在高热、潮湿地区贮存,有效氯含
  • 图谱信息:二氯异氰尿酸钠(2893-78-9)红外图谱(IR2) 二氯异氰尿酸钠(2893-78-9)Raman光谱 二氯异氰尿酸钠(2893-78-9)核磁图( 13 CNMR) 二氯异氰尿酸钠(2893-78-9)红外图谱(IR1)
  • 稳定性:Stable. Oxidizing agent - contact with combustible material may lead to fire. Incompatible with strong bases, strong oxidizing agents(??) Reacts readily with many nitrogen-containing compounds to form explosive nitrogen triiodide. Moisture-sensitive.

系列性分类