2-Nitrobiphenyl 2-硝基联苯

CAS 86-00-0 MFCD00007126

化学结构图

86-00-0
SMILES: O=[N+]([O-])c1ccccc1-c1ccccc1

化学属性

Mol. FormulaC12H9NO2
Mol. Weight199
Autoignition Point356 °F
Vapor Density5.9 (vs air)
Boiling Point170°C/13mmHg(lit.)
Vapor Pressure2 mmHg ( 140 °C)
Melting Point36-38 ºC
Refractive index1.613-1.615
Flash Point179 ºC
Solubility不溶
Density1.44

别名和识别编码

Chemical Name2-Nitrobiphenyl
Synonym o-Aminophenylbenzene TIMTEC-BB SBB008510 邻氨基联苯 2-BIPHENYLYLAMIN 1’-Biphenyl,2-nitro-1 O-AMINOBIPHENYL 2-BIPHENYLAMINE O-AMINODIPHENYL 2-硝基-1,1’-联苯 鄰胺聯苯 2-nitro-bipheny [1,1'-BIPHENYL]-2-AMINE O-PHENYLANILINE ONB Nitrodiphenyl 2-nitro-1’-biphenyl 2-BIPHENYLYLAMINE o-Nitrobiphenyl 邻苯基苯胺 Biphenyl, 2-nitro- 2-硝基联苯 ORTHO-NITRODIPHENYL CP 368 邻硝基联苯 1-Nitro-2-phenylbenzene 1,1'-Biphenyl, 2-nitro- 2-联苯基胺 2-PHENYLANILINE O-XENYLAMINE 邻氨基苯胺 2-氨基联苯基,97% 2-PHENYLANILIN 邻丙基苯胺 Onb o-Nitrobiphenyl 2-NITROBIPHENYL 2-phenylnitrobenzene 2-Nitrobiphneyl o-Nitrodiphenyl 2-氨基联苯 2-Nitro-1,1’-biphenyl 2-氨基联苯基 2-Phenylnitrobenzene o-Nitrodiphenyl ORTHO-NITROBIPHENYL 2-nitro-biphenyl AMINOBIPHENYL(2-) O-NITRODIPHENYL TIMTEC-BB SBB003867 2-Nitro-1,1'-biphenyl 2-NITRODIPHENYL 2-AMINODIPHENYL 2-Nitrobiphenyl 2-联苯胺 O-BIPHENYLAMINE AKOS BBS-00003669 2-Nitrodiphenyl 2-AMINOBIPHENYL cp368 1,1'-Biphenyl, 2-nitro-
MDL NumberMFCD00007126
CAS Number86-00-0
PubChem Substance ID6829
EC Number201-646-8
Reaxys-RN1818699
Beilstein Registry Number5,582
Merck Number6591
Chemical Name Translation2-硝基联苯
Wiswesser Line NotationWNR BR
LabNetwork Molecule IDLN00198405
InChIInChI=1S/C12H9NO2/c14-13(15)12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemi

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H332 Harmful if inhaled 吸入有害
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSDV5530000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P304+P312
  • P304+P340
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes Xn
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S2 Keep out of the reach of children 避免儿童触及;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R52/53
  • R21/22/36/37/38/40
  • R20 Harmful by inhalation 吸入有害
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1580 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 29,1,1947

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1230 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 29,1,1947

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Kidney
DOSE/DURATION           : 80 ug/L
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   37,873,1978

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 3 mmol/L
REFERENCE :
   SinJF# Personal Communication from J.F. Sina, Merck Institute for
   Therapeutic Research, West Point, PA 19486, Oct. 26, 1982
   Volume(issue)/page/year: 26OCT1982

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 150 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 203,155,1988

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 20 ug/plate
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   37,873,1978

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 428 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 272,145,1992

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 110 umol/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 3,193,1988

其他信息

  • 毒性分级:中毒
  • 图谱信息:邻氨基联苯(90-41-5)Raman光谱 邻氨基联苯(90-41-5)核磁图( 1 HNMR) 邻氨基联苯(90-41-5)红外图谱(IR2) 邻氨基联
  • 蒸气压:2 mm Hg ( 140 °C)
  • 邻氨基联苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0467 2-氨基联苯[用于糖的测定] 2-Aminobiphenyl [for Sugar determination] 500G 6380元 2014/06/02 B0467 2-氨基联苯[用于糖的测定] 2-Aminobiphenyl [for Sugar determination] 25G 781元 2010/06/21 103220050 邻氨基联苯 2-Aminobiphenyl 98% 5 GR 421元
  • 下游产品:糖精 --> 咔唑 --> 2-(氯磺酰基)苯甲酸甲酯 --> 邻苯基苯酚 --> 糖精钠 --> 糖精钠
  • Sigma Aldrich:86-00-0(sigmaaldrich)
  • 方法一:以邻硝基联苯为原料,经还原而得:将邻硝基联苯、乙醇、氯化亚锡于水浴回流3h,回收乙醇,将剩余物冷却,加入40%液碱使呈强碱性,分出油层,水层用乙醚提取,将提取液用无水氯化钙干燥,过滤回收乙醚,用乙醇洗得粗品,再将粗品减压蒸馏而得成
  • 类别:有毒物品
  • TCI Shanghai:2-硝基联苯 2-Nitrobiphenyl,>;98.0%(GC)(86-00-0)
  • 可燃性危险特性:明火可燃; 受热放出有毒氧化氮气体
  • Acros Organics:2-硝基联苯 2-Nitrobiphenyl, 97%(86-00-0)
  • MSDS 信息:2-氨基联苯(90-41-5).msds
  • 2-硝基联苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0194 2-硝基联苯 2-Nitrobiphenyl 500G 5220元 2014/06/02 N0194 2-硝基联苯 2-Nitrobiphenyl 25G 645元
  • 蒸气密度:5.9 (vs air)
  • MOL 文件:86-00-0.mol
  • 用途一:用于有机合成,也用作医药、染料中间体和防霉剂
  • 外观性质:微黄色至淡红色液体或结晶。
  • 图谱信息:2-硝基联苯(86-00-0)红外图谱(IR1) 2-硝基联苯(86-00-0)核磁图( 13 CNMR) 2-硝基联苯(86-00-0)红外图谱(IR2) 2-硝基联苯(86-00-0)Raman光谱 2-硝基联苯(86-00-0)核磁图( 1 HNMR) 2-硝基联苯(86-00-0)质谱(MS)
  • 储运特性:库房通风低温干燥
  • 外观性质:浅紫色结晶。
  • 海关编码:29214980
  • Sigma Aldrich:90-41-5(sigmaaldrich)
  • TCI Shanghai:2-氨基联苯[用于糖的测定] 2-Aminobiphenyl [for Sugar determination],>;99.0%(GC)(90-41-5)
  • Alfa Aesar:2-氨基联苯基,97% 2-Aminobiphenyl, 97%(90-41-5)
  • 上游原料:氯化亚锡 --> 2-硝基联苯 --> 联苯乙醇
  • A
  • MSDS 信息:2-硝基联苯(86-00-0).msds
  • 下游产品:邻氨基联苯
  • 用途二:制造咔唑树脂及合成橡胶。癌症研究。化学分析。糖类的测定
  • {Chemic
  • 急性毒性:口服-大鼠 LD50: 2340 毫克/公斤; 口服-兔子 LD50: 1020 毫克/公斤

系列性分类


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