2-Methyl-4-Nitroaniline 2-甲基-4-硝基苯胺

CAS 99-52-5 MFCD00007734

化学结构图

99-52-5
SMILES: Cc1cc([N+](=O)[O-])ccc1N

化学属性

Mol. FormulaC7H8N2O2
Mol. Weight152.15
Melting Point130-132
Density1.1586
TSCAYes
Solubility<0.1 G/100 ML AT 22 ºC
Flash Point157.2℃

别名和识别编码

Chemical Name2-Methyl-4-Nitroaniline
CAS Number99-52-5
Alfabeta NameMETHYLNITROANILINE 24---
MDL NumberMFCD00007734
Synonym Fast Red RL Base {LY} Fast Red RL Base Kako Red RL Base MNA (optical crystal) Sanyo Fast Red RL Base Spectrolen Spectrolene Red RL {} {LY} Fast Red RL Base {} {} {LY} Fast Red RL Base {} {} {} {LY} Fast Red RL Base {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fast Red RL Base {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID7441
EC Number202-762-1
Beilstein Registry Number775772
Reaxys-RN775772
Chemical Name Translation2-甲基-4-硝基苯胺
InChIKeyXTTIQGSLJBWVIV-UHFFFAOYSA-N
LabNetwork Molecule IDLN00171877
InChIInChI=1S/C7H8N2O2/c1-5-4-6(9(10)11)2-3-7(5)8/h2-4H,8H2,1H3
Canonical SMILESNC1=CC=C([N+]([O-])=O)C=C1C
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分类

  • Amines, Building Blocks, C7, Chemical Synthesis, Materials Science, NLO Chromophores and Intermediates, Nitrogen Compounds, Non-Linear Optical (NLO) Materials, Organic Building Blocks, Organic and Printed Electronics, Photonic and Optical Materials
  • {SNA} Amines, Building Blocks, C7,
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C7, Chemical Synthesis, NLO Chromophores and Intermediates, Nitrogen Compounds, Non-Linear Optical (NLO) Materials, Organic Building Blocks, Organic and Printed Electronics, Photonic and Optical Materials, 材料科

产品应用

  • A red azoic dye.

相关文献及参考

  • Beilstein: 12,IV,1809
  • Short: IV/1a
  • Short: IV/4
  • Altenburger, R., et al.: Environ. Toxicol. Chem., 24, 324 (2005),
  • Hoover, K., et al.: Chem. Res. Toxicol., 18, 1497 (2005),
  • Short: IV/16
  • Gonzalez, M., et al.: Bioorg. Med. Chem., 13, 1775 (2005),

安全信息

Warnings IRRITANT 危化品目录(2015) 危险化学品
GHS Symbol
WGK Germany3
Hazard statements
  • H301+H311+H331
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T,N,Xi T,N
RTECSXU8210000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P403+P233
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P308+P313
  • P332+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P310
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P301+P310+P330
  • P337+P313
  • P304+P340+P311
  • P302+P350
Signal word
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
UN Number
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2500 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   54DEAI "Occupational Health in the Chemical Industry, Proceedings of the
   International Congress, 11th, Alberta, Canada, 1983," Oxford, R.R., et al.,
   eds., Calgary, Alberta, Canada, Univ. of Calgary, 1984
   Volume(issue)/page/year: -,497,1984

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 上游原料:氢氧化钠 --> 碳酸氢钠 --> 亚硫酸钠 --> 甲基磺酰氯 --> 邻甲基苯胺 --> 苯磺酰氯
  • 可燃性危险特性:明火可燃;高热分解; 释放有毒氮氧化物烟雾
  • Acros Organics:2-甲基-4-硝基苯胺/对硝基邻甲苯胺 2-Methyl-4-nitroaniline, 99%(99-52-5)
  • 方法一:采用邻甲苯胺与对甲磺酰氯为原料，经缩合、硝化、水解，中和及过滤干燥而得。原料消耗定额：邻甲苯胺（工业品）945kg/t、烧碱（100%）1350kg/t、苯磺酰氯（工业品）1650kg/t、小苏打（工业品）40kg/t、氯苯（工业品）460kg/t、硫酸（100%）3100kg/t、硝酸（98%）680kg/t、氨水（20%）6230kg/t、亚硝酸钠10kg/t、亚硫酸钠（工业品）26kg/t。
  • Alfa Aesar:2-甲基-4-硝基苯胺,98% 2-Methyl-4-nitroaniline, 98%(99-52-5)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • TCI Shanghai:2-甲基-4-硝基苯胺 2-Methyl-4-nitroaniline,>;99.0%(GC)(99-52-5)
  • 海关编码:29214300
  • MSDS 信息:对硝基邻甲苯胺(99-52-5).msds
  • 用途二:该品是冰染染料色基（红色基 RL），主要用于棉、麻纤维织物的染色和印花显色，也可用于涂料的生产。
  • Hazard Note:Irritant
  • Sigma Aldrich:99-52-5(sigmaaldrich)
  • MOL 文件:99-52-5.mol
  • 外观性质:黄色晶体。
  • 4-硝基-2-甲苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010364 2-甲基-4-硝基苯胺;4-硝基邻甲苯胺;2-氨基-5-硝基甲苯 100g 198元 2011/04/16 N0116 2-甲基-4-硝基苯胺 2-Methyl-4-nitroaniline 25G 263元 2011/04/16 N0116 2-甲基-4-硝基苯胺 2-Methyl-4-nitroaniline 500G 1300元
  • 图谱信息:4-硝基-2-甲苯胺(99-52-5)核磁图( 1 HNMR) 4-硝基-2-甲苯胺(99-52-5)Raman光谱 4-硝基-2-甲苯胺(99-52-5)红外图谱(IR1) 4-硝基-2-甲苯胺(99-52-5)质谱(MS) 4-硝基-2-甲苯胺(99-52-5)核磁图( 13 CNMR) 4-硝基-2-甲苯胺(99-52-5)红外图谱(IR2)
  • 色指数:37100
  • 灭火剂:二氧化碳、泡沫、砂土、雾状水
  • 用途一:主要用于棉、麻纤维织物的染色和印花显色，也用于涂料的生产
  • 下游产品:4-溴-2-甲基苯腈 --> 4-氟-N-甲基苯胺 --> 2-溴-6-甲基-4-硝基苯胺 --> 吲唑-5-甲腈 --> 3,5-二氯-1H-吲唑 --> 3-氯-5-氨基-1H-吲唑 --> 3-碘-5-硝基-1H-吲唑 --> 5-氨基吲唑 --> 3-氯-5-硝基-1H-吲唑 --> 冰染重氮组分 34 --> 2,5-二硝基苯甲酸 --> 5-硝基吲唑
  • 类别:有毒物品

系列性分类

  1. C7 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. C10 to C11 - Amines
  1. Materials Science 材料科学
  2. Organic Nonlinear Optical Materials

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