N-(2-Hydroxyethyl)Ethylenediamine 羟乙基乙二胺

CAS 111-41-1 MFCD00008170

化学结构图

111-41-1
SMILES: NCCNCCO

化学属性

Mol. FormulaC4H12N2O
Mol. Weight104
Refractive index1.4830 to 1.4880
Boiling Point238-240
Density1.03
Flash Point125°C(lit.)
TSCAYes
Melting Point-28°C
Vapor Density3.6 (vs air)
Solubility可溶
Stability易吸潮
Appearance 无色、浅黄色透明粘稠液体。有吸湿性，呈强碱性，微有氨气味。 能与水和醇相混溶，微溶于醚。

别名和识别编码

Chemical NameN-(2-Hydroxyethyl)Ethylenediamine
Synonym N-(2-Hydroxyethyl)-ethylendiamin Monoethanolethylenediamine {Chemicalbook} 1-(2-Hydroxyethylamino)-2-aminoethane {Chem { N-2-hydroxyethylethylene 2-(2-amino-ethylamino)-ethanol N-(Aminoethyl)ethanolamine N-B-HYDROXYETHYLETHYLENEDIAMINE 2-(2-Aminoethylamino N-(β-Hydroxyethyl)-1,2-ethanediamine 氨乙基-乙醇胺 (2-Aminoethyl)ethanolamine 2-[(2-Aminoethyl)amino]ethan 羟乙基乙 N-(2'-Hydroxyethyl)ethylenediamine 1-[2-(Hydroxyethyl)amino]-2-aminoe β-羟乙基二胺 2-((2-hydroxyethyl)amino)ethylamine N-(2-Hydroxyethy)-ethylendiamin AMINOETHYETHANOLAMINE AMINOETHYLETHANOLAMIN N-(2-Hydroxyethyl)-1,2-ethanediamine 2-(2-Hydroxyethylamino)ethylamine 2-(
CAS Number111-41-1
PubChem Substance ID87561952
EC Number203-867-5
Beilstein Registry Number4,286
MDL NumberMFCD00008170
Reaxys-RN506012
Chemical Name Translation羟乙基乙二胺
Wiswesser Line NotationZ2M2Q
LabNetwork Molecule IDLN00119312
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分类

  • {SNA} Amino Alcohols, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; alcohol; 1fragment
  • Amino Alcohols, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

产品应用

  • 主要用做阳离子、两性离子表面活性剂的原料；亦可作为环氧树脂固化剂、其它精细化工产品的原料。

相关文献及参考

  • Short: III/47
  • Beilstein:4,286
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H303+H313
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C,T C T
RTECSKJ6300000
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P308+P313
  • P305+P351+P338+P310
  • P303+P361+P353
  • P304+P340+P310
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
Signal word
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R34 Causes burns 会导致灼伤
UN Number 2735
Storage condition Air Sensitive & Hygroscopic 密封保存
Packing GroupII
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3550 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EVSSAV Environmental Space Science.  English Translation of Kosmicheskaya
   Biologiya Meditsina. 1967-70.  Volume(issue)/page/yea

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 417 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 120 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EVSSAV Environmental Space Science.  English Translation of Kosmicheskaya
   Biologiya Meditsina. 1967-70.  Volume(issue)/page/year: 2,289,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3560 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 7/19/1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 7/19/1965

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2800 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9(Suppl
   9),1,1987

其他信息

  • 毒性分级:中毒
  • 海关编码:29221980
  • 用途四:用于生产染料、树脂、橡胶、浮选剂、杀虫剂、表面活性剂，配制的缓蚀剂1017用于石油化工生产。该品为环氧树脂的优良低毒常温固化剂，明显优于乙二胺。该品与环氧树脂配用，广泛用于粘接各种金属和非金属部件，配制防腐蚀环氧涂料，浇铸电缆接头和其他机械电器零件。
  • Sigma Aldrich:111-41-1(sigmaaldrich)
  • 溶于水和醇，微溶于醚。具吸湿性，强碱性，能吸收空气中的二氧化碳。微有氨气味。
  • Acros Organics:N-(2-羟乙基)乙二胺 2-(2-Aminoethylamino)ethanol, 97%(111-41-1)
  • 上游原料:乙二胺
  • 蒸气密度:3.6 (vs air)
  • 急性毒性:口服-大鼠LD50: 3000 毫克/公斤; 口服-小鼠LD50:3550 毫克/公斤
  • 用途五:主要用做阳离子、两性离子表面活性剂的原料；亦可作为环氧树脂固化剂、其它精细化工产品的原料。
  • 羟乙基乙二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30101326 N-（2-羟乙基）乙二胺;N-(2-氨基乙基)乙醇胺 100ml 37.7元 2011/04/16 A0299 2-(2-氨乙基氨基)乙醇 2-(2-Aminoethylamino)ethanol 500ML 295元 2011/04/16 A0299 2-(2-氨乙基氨基)乙醇 2-(2-Aminoethylamino)ethanol 25ML 150元
  • 类别:易燃液体
  • 下游产品:多种表面活性剂复配物 --> XCG-CA-2椰油基羧甲基钠型醋酸盐 --> N-月桂酰基-N'-羟乙基乙二胺丙酸盐 --> 月桂基羟乙基羟丙基咪唑啉磺酸盐 --> N-蓖麻油酰基-N-羟乙基-N-羧乙基乙二胺乙酸内盐
  • 敏感性:Hygroscopic
  • 用途三:用作塑料的固化剂
  • 可燃性危险特性:易燃;接触大表面积的硝化纤维起火;燃烧产生有毒氮氧化物烟雾
  • 储运特性:库房通风低温干燥
  • 用途二:用于有机合成
  • 用途一:用于洗发香波、润滑剂、油田缓冲剂、树脂合成、纺织助剂、咪唑啉两性表面活性剂等
  • Alfa Aesar:N-(2-羟乙基)乙二胺,99% N-(2-Hydroxyethyl)ethylenediamine, 99%(111-41-1)
  • 刺激数据:皮肤-兔子445 毫克 轻度; 眼睛-兔子50 毫克 重度
  • MOL 文件:111-41-1.mol
  • TCI Shanghai:N-(2-氨基乙基)乙醇胺 2-(2-Aminoethylamino)ethanol,>;99.0%(GC)(111-41-1)
  • MSDS 信息:2-(2-Aminoethylamino)ethanol(111-41-1).msds
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 图谱信息:羟乙基乙二胺(111-41-1)核磁图( 1 HNMR) 羟乙基乙二胺(111-41-1)红外图谱(IR1) 羟乙基乙二胺(111-41-1)质谱(MS) 羟乙基乙二胺(111-41-1)Raman光谱 羟乙基乙二胺(111-41-1)核磁图( 13 CNMR)
  • 方法一:由乙二胺与环氧乙烷反应而得。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Amino Alcohols - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols
  6. C9 to C30