Divinyl sulphone 乙烯砜

CAS 77-77-0 MFCD00008623

化学结构图

77-77-0
SMILES: C=CS(=O)(=O)C=C

化学属性

Mol. FormulaC₄H₆O₂S
Mol. Weight118.16
Boiling Point234 °C(lit.)
Melting Point-26 °C(lit.)
Refractive indexn20/D 1.476(lit.)
Density1.177 g/mL at 25 °C(lit.)
Flash Point102°(215°F)
TSCANo
Solubility>=10 G/100 ML AT 17 ºC

别名和识别编码

Chemical NameDivinyl sulphone
CAS Number77-77-0
Alfabeta NameDIVINYLSULFONE
MDL NumberMFCD00008623
Synonym (CH2=CH)2SO2 1,1'-Sulfonylbisethen 1,1'-Sulfonylbisethene; Divinylsulfone; Vinyl sulfone 1,1'-Sulphonylbisethene 1,1'-sulfonylbisethene 1,1’-sulfonylbis-ethen 1,1’-磺酰基二乙烯 1-(Vinylsulfonyl)ethylene Bis(ethenyl)sulfone DIVINYL SULFONE DIVINYL SULFONE, STAB. DIVINYL SULPHONE Divinyl Sulfone (Stabilized with Hydroquinone) {uni_hamburg} TL 797 VINYL SULFONE VINYL SULPHONE VS Vinyl sulfone Vinyl sulfone or divinyl sulfone divinyl sulfone {} {uni_hamburg} Sulfone, divinyl- {} {} {uni_hamburg} Ethenesulfonyl-ethene {} {} {} {Chemicalbook} Ethene, 1,1'-sulfonylbis- {} {} {} {} { {} {} {} {} {uni_hamburg} Ethene, 1,1'-sulfonylbis- {} {} {} {} {} {Chemicalbook
PubChem Substance ID6496
EC Number201-057-6
Beilstein Registry Number1071329
Chemical Name Translation乙烯砜
Wiswesser Line Notation1U1SW1U1
InChIInChI=1S/C4H6O2S/c1-3-7(5,6)4-2/h3-4H,1-2H2
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分类

  • {SA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, DIG-DY, Organic Building Blocks, Sulfones, Sulfur Compounds
  • {SNA} Bioactive Small Molecules, Cell Biology, DIG-DY, Materials Science, Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers
  • {SNA} Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers, 材料科学
  • {uni_hamburg} no charge; sulfone; 1fragment

相关文献及参考

  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling consta

安全信息

Warnings KEEP COLD, TOXIC, CORROSIVE 危化品目录(2015) 危险化学品
WGK Germany3
RTECSKM7175000
Packing GroupI
UN Number UN 2810 6.1/PG 1 UN2927 2810
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R27 Very toxic in contact with skin 与皮肤接触极毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S27/28
Hazard Codes T+ T+,T,C
GHS Symbol
Hazard statements
  • H300 Fatal if swallowed 吞食致命
  • H300+H310
  • H310 Fatal in contact with skin 皮肤接触致命
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P330+P331
  • P302+P350
  • P302+P352
  • P302+P352+P310
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Class6.1
Storage condition 2-8°C 4
Restrict 剧毒 {} 剧毒化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 32 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 5 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0570940

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcut

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 990 mg/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year: No.9-4-1-9,19

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 14 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/yea

其他信息

  • MSDS 信息:Vinyl sulfone(77-77-0).msds
  • MOL 文件:77-77-0.mol
  • 海关编码:29309070
  • 乙烯砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K4392001 二乙烯砜 (+4℃)(剧毒) 10ml 538元
  • Alfa Aesar:二乙烯基砜,0.05%对羟基苯酚作稳定剂 Divinyl sulfone, 97%, stab. with 0.05% hydroquinone(77-77-0)
  • F:10
  • Sigma Aldrich:77-77-0(sigmaaldrich)
  • 图谱信息:乙烯砜(77-77-0)质谱(MS) 乙烯砜(77-77-0)红外图谱(IR2) 乙烯砜(77-77-0)核磁图( 1 HNMR) 乙烯砜(77-77-0)红外图谱(IR1) 乙烯砜(77-77-0)核磁图( 13 CNMR) 乙烯砜(77-77-0)红外图谱(IR3)

系列性分类


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