Diallyldisulfide 二烯丙基二硫

CAS 2179-57-9 MFCD00008656

化学结构图

2179-57-9
SMILES: C=CCSSCC=C

化学属性

Mol. FormulaC6H10S2
Mol. Weight146.27
Refractive index1.5400 to 1.5450
Boiling Point180-195 °C at 760 mmHg
Density1.01
Flash Point62°C(lit.)
TSCAYes
Vapor Density>;5 (vs air)
Vapor Pressure1 mmHg ( 20 °C)
Appearance 淡黄色液体。呈大蒜特殊气味，有催泪性。沸点138～139℃，或79℃(2133Pa)。不溶于水，溶于大多数普通有机溶剂。 天然品存在于生白菜、洋葱、大蒜、细香葱等中。
Stability对热和空气敏感
Melting PointN/A

别名和识别编码

Chemical NameDiallyldisulfide
Synonym Diallyl disulfide {LY} Diallyl disulfide {} {LY} Diallyl disulfide {} {} {LY} Diallyl disulfide {} {} {} {LY} Diallyl disulfide {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diall
CAS Number2179-57-9
PubChem Substance ID16590
EC Number218-548-6
Beilstein Registry Number1699241
MDL NumberMFCD00008656
Reaxys-RN1699241
Chemical Name Translation二烯丙基二硫
LabNetwork Molecule IDLN00162843
InChIInChI=1S/C6H10S2/c1-3-5-7-8-6-4-2/h3-4H,1-2,5-6H2
Canonical SMILESC=CCSSCC=C
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分类

  • {Chemicalbook} 食品添加剂: 食用香料（增香剂）: 天然等同香料和人造香
  • {SNA} Building Blocks, Chemical Synthesis, Oils and Resin-derived, Organic Building Blocks, Phytochemicals by Chemical Classification, Sulfides/Disulfides, Sulfur Compounds, 细胞生物学, 营养研究
  • {SNA} Building Blocks, Cell Biology, Chemical Synthesis, Nutrition Research, Oils and Resin-derived, Organic Building Blocks, Phytochemicals by Chemical Classification, Sulfides/Disulfides, Sulfur Compounds
  • {SNA} A - D, A-B, A-D, Alphabetical Listings, Certified Food Grade Products, Flavors and Fragrances,

相关文献及参考

  • Beilstein: 1,IV,2098

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 Xn
RTECSBB1000000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2810
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R10 Flammable 易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 260 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   26,297,1988

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   26,297,1988

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 8 mg/L
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   35,379,1997

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 10 mg/L
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   35,379,1997

其他信息

  • 蒸气压:1 mm Hg ( 20 °C)
  • FEMA:2028
  • 毒性:GRAS(FEMA)。
  • TCI Shanghai:二烯丙基二硫醚 Diallyl Disulfide,>;75.0%(GC)(2179-57-9)
  • Alfa Aesar:二硫化二烯丙基,tech.80% Diallyl disulfide, tech. 80%(2179-57-9)
  • 二烯丙基二硫价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0071 二烯丙基二硫醚 Diallyl Disulfide 25G 467元 2010/06/21 293320250 二烯丙基二硫 Diallyldisulfide 70%, remainder mainly diallyl sulfide 25 GR 471元 2010/06/21 293321000 二烯丙基二硫 Diallyldisulfide 70%, remainder mainly diallyl sulfide 100 GR 1272元
  • Acros Organics:二烯丙基二硫醚 Diallyldisulfide, remainder mainly diallyl sulfide, 70%(2179-57-9)
  • 用途二:食品用香料。
  • 使用限量:FEMA(mg/kg)：调味品6.5；肉类7.0。 FDA，§172．515(2000)：适量为限。
  • 蒸气密度:>;5 (vs air)
  • 类别:有毒物品
  • 图谱信息:二烯丙基二硫(2179-57-9)红外图谱(IR1) 二烯丙基二硫(2179-57-9)核磁图( 13 CNMR) 二烯丙基二硫(2179-57-9)质谱(MS)
  • MOL 文件:2179-57-9.mol
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • MSDS 信息:Allyl disulfide(2179-57-9).msds
  • F:13
  • 参考质量标准:FAO/WHO，1999 含量(GT-10-4) ≥80% 折射率( D 20 ) 1.537～1.551 相对密度(d 25 25 ) 0.998～1.015
  • 急性毒性:口服-大鼠LD50: 260毫克/公斤
  • 溶于乙醇、氯仿或乙醚，不溶于水。具有强烈的大蒜味，味辣。
  • Sigma Aldrich:2179-57-9(sigmaaldrich)
  • 上游原料:烯丙硫醇
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量（g/kg） 最大允许残留量（g/kg） 烯丙基二硫醚 食品 食品用香料 用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
  • 毒性分级:高毒
  • 可燃性危险特性:可燃;燃烧产生有毒硫氧化物烟雾
  • 方法一:由烯丙基硫醇与碘在乙醇和吡啶存在下氧化而得。
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 用途三:广谱抗菌药。治疗消化道、呼吸道及阴道的霉菌感染，如菌痢、百日咳等均有效。
  • 用途一:用作食品添加剂、医药中间体

系列性分类

  1. Application Areas 应用领域分类
  2. Flavors and Fragrances 香精香料
  3. Halal Certified Products - Flavors and Fragrances
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfides/Disulfides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol Esters - Sulfur Compounds

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