Ethylene glycol diethyl ether 乙二醇二乙醚

CAS 629-14-1 MFCD00009253

化学结构图

629-14-1
SMILES: CCOCCOCC

化学属性

Mol. FormulaC6H14O2
Mol. Weight118
Density0.842
Refractive index1.3910 to 1.3950
Flash Point35°C(lit.)
TSCAYes
Boiling Point121
Melting Point-74
Solubility略溶于水
Vapor Pressure9.4 mmHg
Stability对光敏感

别名和识别编码

Chemical NameEthylene glycol diethyl ether
Synonym 1,2-DIETHOXYETHANE 1,2-Diethoxyethane 1,2-Diethoxyethane,98% 1,2-diethoxyethane 1,2-ethanediol,diethylether 1,2-二一氧基硅烷 1,2-二乙氧基乙烷 1,2-二乙氧基乙烷,二乙基溶纤剂 2-ethoxyethyl ethyl ether 2-ethoxyethylethylether 3,6-Dioxaoctane DEE DIETHYL CELLOSOLVE Diethyl cellosolve Diethylether ethylenglykolu Diethylglycol Ethane, 1,2-diethoxy- Ethane-1,2-diol diethyl ether Ethylene Glycol Diethyl Ethylene glycol diethyl ether EthyleneGlycolDiethylEtherC6H14O2 Glyme-1 Hisolve EME diethyletherethylenglykolu ethykene glycol diethyl ether ethylene glycol diethyl ether ethyleneglycoldlethylether {} {} {} {Chemica {} {} {} {} {uni_ha
MDL NumberMFCD00009253
CAS Number629-14-1
EC Number211-076-1
Beilstein Registry Number1732917
PubChem Substance ID12375
Reaxys-RN1732917
Chemical Name Translation乙二醇二乙醚
Wiswesser Line Notation2O2O2
LabNetwork Molecule IDLN00227163
InChIInChI=1S/C6H14O2/c1-3-7-5-6-8-4-2/h3-6H2,1-2H3
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分类

  • {uni_hamburg} no charge; ether; 1fragment
  • {SNA} ACS and Reagent Grade Solvents, Amber Glass Bottles, Reagent, Reagent Grade Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents
  • {SNA} Amber Glass Bottles, Reagent, Solvent Bottles, Solvent Packaging Options, Solvents

产品应用

  • 有机合成反应介质。溶剂。清洁剂。稀释剂。

相关文献及参考

  • Short: IV/10A
  • Beilstein:1,468
  • Short: III/38B

安全信息

RTECSKI1225000
Packing GroupII
UN Number
Risk Statements
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
  • R11 Highly flammable 非常易燃
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R36 Irritating to eyes 刺激眼睛
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R60 May impair fertility 可能降低生殖能力
Safety Statements
GHS Symbol
WGK Germany2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P318
  • P332+P313
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes F,T T
Hazard Class3
Storage condition Flammables area 密封阴凉干燥避光保存。
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 2440 mg/kg
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Gastrointestinal - other changes
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 23,259,1941

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4390 mg/kg
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Gastrointestinal - other changes
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 23,259,1941

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,343,1949

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 10 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB88-134093

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 23640 mg/kg
SEX/DURATION            : female 7-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 57,141,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 1400 mg/kg
SEX/DURATION            : female 6-19 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   19,15,1992

TYPE

其他信息

  • 用途四:有机合成反应介质。溶剂。清洁剂。稀释剂。
  • 乙二醇二乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80061928 乙二醇二乙醚;1,2-二乙氧基乙烷;二乙基溶纤剂 500ml 69元 2011/04/16 D0456 1,2-二乙氧基乙烷 1,2-Diethoxyethane 25ML 229元 2011/04/16 D0456 1,2-二乙氧基乙烷 1,2-Diethoxyethane 500ML 1130元
  • 毒性分级:中毒
  • 海关编码:29091900
  • 图谱信息:乙二醇二乙醚(629-14-1)核磁图( 1 HNMR) 乙二醇二乙醚(629-14-1)Raman光谱 乙二醇二乙醚(629-14-1)质谱(MS) 乙二醇二乙醚(629-14-1)核磁图( 13 CNMR) 乙二醇二乙醚(629-14-1)红外图谱(IR1) 乙二醇二乙醚(629-14-1)红外图谱(IR2)
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 刺激数据:眼睛- 兔子 100 毫克 重度
  • TCI Shanghai:1,2-二乙氧基乙烷 1,2-Diethoxyethane,>;97.0%(GC)(629-14-1)
  • 微有醚的气味。对稀酸稳定,强酸不稳定。能与乙醇、乙醚、丙酮、异丙醚、甲苯、庚烷、1,2-二氯乙烷、乙酸乙酯、蓖麻油、松油等混溶,20℃时水中溶解度为21%。易燃。低毒,半数致死量(大鼠,经口)4392mg/kg。易燃。
  • 用途三:用作硝化纤维素、橡胶、树脂等的溶剂以及有机合成的反应介质。
  • 急性毒性:口服- 大鼠 LD50: 4390 毫克/ 公斤; 口服- 豚鼠 LD50: 2440 毫克/ 公斤
  • 类别:易燃液体
  • 微有醚的气味。对稀酸稳定,强酸不稳定。能与乙醇、乙醚、丙酮、异丙醚、甲苯、庚烷、1,2-二氯乙烷、乙酸乙酯、蓖麻油、松油等混溶,20℃时水中溶解度为21%。易燃。低毒,半数致死量(大鼠,经口)4391mg/kg。易燃。
  • 用途一:用作硝化纤维素、橡胶、树脂等的溶剂及有机合成介质
  • 用途二:用作溶剂
  • MOL 文件:629-14-1.mol
  • 外观性质:无色液体,稍有醚的气味。
  • Sigma Aldrich:629-14-1(sigmaaldrich)
  • 可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生有刺激烟雾
  • 微有醚的气味。对稀酸稳定,强酸不稳定。能与乙醇、乙醚、丙酮、异丙醚、甲苯、庚烷、1,2-二氯乙烷、乙酸乙酯、蓖麻油、松油等混溶,20℃时水中溶解度为21%。易燃。低毒,半数致死量(大鼠,经口)4390mg/kg。易燃。
  • Acros Organics:乙二醇二乙醚 Ethylene glycol diethyl ether, 99%(629-14-1)
  • Alfa Aesar:1,2-二乙氧基乙烷,98% 1,2-Diethoxyethane, 98%(629-14-1)
  • MSDS 信息:乙二醇二乙醚(629-14-1).msds
  • 蒸气压:9.4 mm Hg ( 20 °C)
  • 方法一:由环氧乙烷与乙醇反应而得。

系列性分类


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