Tri-n-butyltin methoxide 三正丁基甲氧基锡
CAS 1067-52-3 MFCD00009419
化学结构图
SMILES: CCCC[Sn](CCCC)(CCCC)OC
化学属性
| Mol. Formula | [CH3(CH2)3]3SnOCH3 |
|---|---|
| Mol. Weight | 321.09 |
| Density | 1.115 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.472(lit.) |
| Flash Point | 98°(208°F) |
| TSCA | No |
| Boiling Point | 97-97.5 °C/0.06 mmHg(lit.) |
| Melting Point | 95-97 ºC |
别名和识别编码
| Chemical Name | Tri-n-butyltin methoxide |
|---|---|
| MDL Number | MFCD00009419 |
| Synonym | Stannane, tributylmethoxy- Tributyl(methoxy)stannane tri-n-butyltin methanolate TRI-N-BUTYLTIN METHOXIDE 三正丁基甲氧基锡 TRI-N-BUTYLTIN METHYLATE Methoxytributylstannane Methoxytri-n-butylstannane Tributylmethoxytin(IV) TRI-N-BUTYLMETHOXYTIN Tri-n-butyl Tin Methoxide(TBTM) Methoxytributylstannane; Tributylmethoxystannane; Tributylmethoxytin; Tributyltin methanolate; Tributyltin methoxide methoxytri-n-butylstannane Tributyltin(IV)methoxide TRIBUTYLTIN METHOXIDE Tributylmethoxystannane |
| EC Number | 213-933-5 |
| CAS Number | 1067-52-3 |
| Beilstein Registry Number | 3600960 |
| PubChem Substance ID | 16683411 |
| Chemical Name Translation | 三正丁基甲氧基锡 |
| LabNetwork Molecule ID | LN00117042 |
| InChI | InChI=1S/3C4H9.CH3O.Sn/c3*1-3-4-2;1-2;/h3*1,3-4H2,2H3;1H3;/q;;;-1;+1 |
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分类
- {SA} Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organotin, Organotins, Solution Deposition Precursors, Tin
- {SNA} Chemical Synthesis, Micro/NanoElectronics, Organometallic Reagents, Organotin, Organotins, Solution Deposition Precursors, Tin, 材料科学
- Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organotin, Organotins, Solution Deposition Precursors, Tin
相关文献及参考
- 1. Aldrichimica Acta 17 , 75, (1984)
- Beil. 4 ,IV,4331
- Fieser 16 ,351
- Aldrich MSDS 1 , 1732:A / Corp MSDS 1 (2), 3401:A / FT-IR 1 (2), 1145:A / FT-IR 2 (3), 4486:A / FT-NMR 1 (3), 742:A / NMR-Reference 2 (2), 1022:C / RegBook 1 (2), 3053:A / Structure Index 1 , 484:B:1
- Catalyst for transesterification under neutral conditions: Bull. Soc. Chim. Fr., 262 (1969).
- Reacts with alcohols, by exchange, to give tri-n-butylstannyl ethers. Those derived from 3-halo alcohols cyclize on heating to give substituted oxetanes: J. Organomet. Chem., 47, 337 (1973):
- Similarly, 4-halo alcohols give tetrahydrofurans: J. Organomet. Chem., 50, 121 (1973).
- Enol acetates are converted to tin enolates which can undergo Pd-catalyzed coupling with aryl bromides to give arylacetones: Chem. Lett., 939 (1982); J. Chem. Soc., Chem. Commun., 344 (1983), and with vinyl bromides to give ß-unsaturated ketones: Bull. Chem. Soc. Jpn., 57, 242 (1984).
- For a review of organotin alkoxides in organic synthesis, see: Synthesis, 56, (1969).
安全信息
- R25 Toxic if swallowed 吞咽有毒
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R21 Harmful in contact with skin 与皮肤接触有害
- R48/23/25
- R50/53
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
- S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H301 Toxic if swallowed 吞食有毒
- H312 Harmful in contact with skin 皮肤接触有害
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H319 Causes serious eye irritation 严重刺激眼睛
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P310
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P301+P310+P330
- P302+P352+P312
其他信息
- Acros Organics:三正丁基甲氧基锡 Tri-n-butyltin methoxide, 97%(1067-52-3)
- Alfa Aesar:三正丁基甲氧基锡,97% Tri-n-butyltin methoxide, 97%(1067-52-3)
- MOL 文件:1067-52-3.mol
- TSCA:No
- 敏感性:Moisture Sensitive
- Sigma Aldrich:1067-52-3(sigmaaldrich)
- 三正丁基甲氧基锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 212090250 三正丁基甲氧基锡 Tri-n-butyltin methoxide 97% 25 GR 449元 2010/06/21 212090100 三正丁基甲氧基锡 Tri-n-butyltin methoxide 97% 10 GR 248元 2010/06/21 212091000 三正丁基甲氧基锡 Tri-n-butyltin methoxide 97% 100 GR 1263元
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