Tris(2,2,2-Trifluoroethyl) Phosphite 三(2,2,2-三氟乙基)亚磷酸酯

CAS 370-69-4 MFCD00009902

化学结构图

370-69-4
SMILES: FC(F)(F)COP(OCC(F)(F)F)OCC(F)(F)F

化学属性

Mol. Formula(CF3CH2O)3P
Mol. Weight328.07
Refractive indexn20/D 1.324(lit.)
Boiling Point130-131 °C/743 mmHg(lit.)
Density1.487 g/mL at 25 °C(lit.)
Flash Point113 ºC

别名和识别编码

Chemical NameTris(2,2,2-Trifluoroethyl) Phosphite
CAS Number370-69-4
PubChem Substance ID136203
Beilstein Registry Number1714041
MDL NumberMFCD00009902
Synonym 三(2,2,2-三氟乙烷基)亚磷酸盐 Phosphorous acid tris-(2,2,2-trifluoro-ethyl) ester Ethanol, 2,2,2-trifluoro-, phosphite (3:1) 三(2,2,2-三氟乙基)亚磷酸酯 tris(trifluoroethyl)phosphite tris(2,2,2-trifluoroethyl) phosphite
Chemical Name Translation三(2,2,2-三氟乙基)亚磷酸酯
InChIKeyCBIQXUBDNNXYJM-UHFFFAOYSA-N
InChIInChI=1S/C6H6F9O3P/c7-4(8,9)1-16-19(17-2-5(10,11)12)18-3-6(13,14)15/h1-3H2
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds

相关文献及参考

  • Beil. 1 ,IV,1371
  • Aldrich MSDS 1 , 1817:B / Corp MSDS 1 (2), 3535:C / FT-IR 2 (1), 1547:B / FT-IR 1 (1), 911:B / FT-NMR 1 (1), 1466:C / RegBook 1 (1), 1093:H / Structure Index 1 , 169:A:2 / Vapor Phase 3 , 839:B
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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