Tert-Amyl Methyl Ether 甲基叔戊基醚

CAS 994-05-8 MFCD00010186

化学结构图

994-05-8
SMILES: CCC(C)(C)OC

化学属性

Mol. FormulaC2H5C(CH3)2OCH3
Mol. Weight102.17
Refractive indexn20/D 1.389(lit.)
Boiling Point85-86 °C(lit.)
Density0.76-0.78 g/mL at 25 °C(lit.)
Flash Point11 °F

别名和识别编码

Chemical NameTert-Amyl Methyl Ether
Synonym (2-Methyl-2-butyl)-methylether 1,1-DIMETHYLPROPYL METHYL ETHER 1,1-Dimethylpropyl methyl ether 1,1-二甲基丙基甲醚 1,1-二甲基丙基甲醚 METHOXYPENTANE™ TAME 甲基2-甲基-2-丁醚 甲基叔戊醚 1,1-二甲基丙基甲醚 TAME 甲基2-甲基-2-丁醚 甲基叔戊醚 2- 2-methoxy-2-methyl-butane 2-methoxy-2-methylbutane tert-Amyl methyl ether tert-Amylmethylether tert-Pentyl methyl ether Ether, methyl tert-pentyl Ether, methyl tert-pentyl METHYL 2-METHYL-2-BUTYL ETHER METHYL-(2-METHYLBUT-2-YL)ETHER METHYL-TERT-AMYL ETHER Methyl 1,1-dimethylpropyl ether Methyl 2-methyl-2-butyl ether Methyl < Methyl tert-amyl ether Methyl tert-amyl ether Methyl tert-pentyl ether {uni_hambur
CAS Number994-05-8
PubChem Substance ID61247
EC Number213-611-4
Beilstein Registry Number1731452
MDL NumberMFCD00010186
Chemical Name Translation甲基叔戊基醚
Merck Number13,618
LabNetwork Molecule IDLN01871725
InChIInChI=1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3
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分类

  • A, A-B, AM to AQ, ASTM D5441, ASTM Petroleum Standards, ASTM Petroleum and Petrochemical, Alcohols, Aliphatic, Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chemical Class, Chromatography, Environmental Standards, Gasoline, Diesel, & Petroleum, Method Specific, Volatiles/ Semivolatiles
  • {uni_hamburg} no charge; ether; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, A,
  • {SNA} Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Short: III/47
  • Merck: 14,612
  • Merck: 14,612 Beilstein: 1,IV,1671
  • Short: III/35E
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301+H311+H331
  • H302 Harmful if swallowed 吞食有害
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H370 Causes damage to organs 导致器官损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,Xn,T F,Xn T
RTECSEK4421000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P303+P361+P353
  • P304+P340
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P330 Rinse mouth. 漱口
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R38 Irritating to skin 刺激皮肤
  • R22 Harmful if swallowed 吞咽有害
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Packing GroupII
Hazard Class3.1
Storage condition Flammables area 储存温度2-8℃
UN Number UN 3271 3/PG 2 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 15,313,1995

其他信息

  • 外观性质:无色透明液体，密度:0.764沸点:85-86 °C折光率:1.3876-1.3896闪点:-11 °C
  • Sigma Aldrich:994-05-8(sigmaaldrich)
  • Acros Organics:叔戊基甲基醚 tert-Amyl methyl ether, 94%(994-05-8)
  • F:3
  • MOL 文件:994-05-8.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C2 to C8 - Ethers
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. A - Alphabetic
  5. AM to AQ - A
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. A - Alphabetic
  5. AM to AQ - A
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. Alpha Sort - Volatiles/ Semivolatiles
  7. A-B - Alpha Sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Gasoline, Diesel, &amp; Petroleum - Chromatography
  5. ASTM Petroleum Standards - Gasoline, Diesel, &amp; Petroleum
  6. ASTM D5441 - ASTM Petroleum Standards
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides

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