• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} Analytical Reagents for General Use, C-D, Puriss p.a., Puriss p.a., 分析/色谱, 分析试剂
• Aliphatics, Alpha Sort, Alphabetic, Amines, Analytical Standards, Analytical/Chromatography, Chemical Class, Chromatography, D, DIA - DIC, Environmental Standards, Volatiles/ Semivolatiles
• {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; 1fragment
• {SNA} Amines, Building Blocks, C12, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
• {SNA} Amines, Building Blocks, C12, Chemical Synthesis,

产品应用

• 广泛用作有机合成中间体，可用于制取染料中间体、橡胶促进剂、硝化纤维漆、杀虫剂、催化剂、防腐剂、气相缓蚀剂及燃料抗氧化添加剂等。也用作萃取剂。二环己胺的脂肪酸盐和硫酸盐具有肥皂的去污性能，用于印染和纺织工业。其金属络合物用作油墨、油漆的催化剂。

相关文献及参考

• Merck:14,3095 Beilstein:12,6
• Merck:14,3095
• Short: III/38B
• Short: II/5
• Short: IV/16
• Forms highly crystalline salts with N-protected amino acids: Liebigs Ann. Chem., 640, 157 (1961).
• Reacts with n-BuLi to give a hindered strong base; cf LDA (see Diisopropyl­amine, A10280), which has been used to promote, e.g. the ɑ -carboethoxylation of ketones; see Diethyl­ dicarbonate, B22753.

安全信息

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2404 mg/kg/48W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 4,659,1958

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 40 gm/kg/52W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
   Liver - tumors
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 4,659,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,468,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   IECHAD Industrial and Engineering Chemistry.  (Washington, DC)  V.15-62,
   1923-70.  For publisher information, see CHMTBL.  Volume(issue)/page/year:
   29,1247,1937

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 373 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,468,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 135 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 4,659,1958

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 200 ug/L
REFERENCE :
   INHEAO Industrial Health.  (National Institute of Industrial Health, 6-21-1
   Nagao, Tama-ku, Kawasaki, 213 Japan)  V.1-    1963- Volume(issue)/page/year:
   9,188,1971

其他信息

• 蒸气压:12 mm Hg ( 37.7 °C)
• F:8-9-23
• 用途一:用于有机合成，也用作杀虫剂、酸性气体吸收剂和钢铁防锈剂
• 用途二:用于制造橡胶硫化促进剂、杀虫剂、催化剂、防腐剂等
• 蒸气密度:6 (vs air)
• 刺激数据:皮肤- 兔子 2 毫克/ 24小时 重度; 眼- 兔子 0.75 毫克/ 24小时 重度
• TCI Shanghai:二环己胺 Dicyclohexylamine,>;99.0%(GC)(101-83-7)
• Alfa Aesar:二环己胺,98% Dicyclohexylamine, 98%(101-83-7)
• MSDS 信息:二环己胺(101-83-7).msds
• MOL 文件:101-83-7.mol
• 有刺激性氨味，易燃、高毒。凝固点：-2℃，与有机溶剂混溶，微溶于水。呈强碱性。
• Acros Organics:二环己基胺 Dicyclohexylamine, 99+%(101-83-7)
• 方法一:以苯胺为原料，在催化剂存在下，高温高压加氢，制得二环己胺。
• 防护措施:本品高毒。具有较强的渗透性臭气，因此，较易被发现。小鼠LD50为2g/kg，大鼠LD50为3.49g/kg。二环己胺可经皮肤吸收，引起皮肤过敏和坏疽，蒸汽可引起恶心和麻醉，但不会引起血液中毒。据报道二环己胺可引起癌症。工作场所空气中最高容许浓度10mg/m3。生产设备应密闭，防止跑、冒、滴、漏。操作现场强制通风，操作人员戴防护用具。
• 急性毒性:口服- 大鼠 LD50: 373 毫克/ 公斤; 腹腔- 小鼠 LD50: 500 毫克/ 公斤
• 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
• 十二氢二苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80048728 二环己胺;十二氢二苯胺 500ml 51元 2011/08/23 30056180 二环己烷 100ml 48.8元 2011/04/16 D0435 二环己胺 Dicyclohexylamine 25ML 117元
• 类别:腐蚀物品
• 职业标准:STEL 1 毫克/ 立方米
• 二环己胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80048728 二环己胺;十二氢二苯胺 500ml 51元 2011/08/23 30056180 二环己烷 100ml 48.8元 2011/04/16 D0435 二环己胺 Dicyclohexylamine 25ML 117元
• 灭火剂:砂土、泡沫、二氧化碳、干粉
• 常规方法:用铁桶密闭包装，净重150kg。贮存于阴凉、通风、干燥处，隔绝火源，装卸运输应按易燃有毒化学品规定贮运。
• 储运特性:库房通风低温干燥; 与酸类分开存放。
• 用途三:广泛用作有机合成中间体，可用于制取染料
• 图谱信息:十二氢二苯胺(101-83-7)质谱(MS) 十二氢二苯胺(101-83-7)Raman光谱 十二氢二苯胺(101-83-7)红外图谱(IR1) 十二氢二苯胺(101-83-7)核磁图( 1 HNMR) 十二氢二苯胺(101-83-7)核磁图( 13 CNMR) 十二氢二苯胺(101-83-7)红外图谱(IR2)
• 下游产品:二环己基碳二亚胺 --> N,N-二环己基-2-苯并噻唑次磺酰胺 --> 溶剂红30 --> 亚硝酸二环己胺
• 毒性分级:高毒
• 爆炸物危险特性:对皮肤和角膜有腐蚀性
• 上游原料:氨基苯
• 凝固点:-2℃
• Sigma Aldrich:101-83-7(sigmaaldrich)
• 外观性质:无色液体，有鱼腥臭。