Diphenyliodonium chloride 氯化二苯基碘
CAS 1483-72-3 MFCD00011909
化学结构图
SMILES: [Cl-].c1ccc([I+]c2ccccc2)cc1
化学属性
| Mol. Formula | C12H10ClI |
|---|---|
| Mol. Weight | 316.57 |
| Melting Point | 233-235 °C |
| TSCA | Yes |
别名和识别编码
| Chemical Name | Diphenyliodonium Chloride |
|---|---|
| Synonym | Diphenyliodonium chloride {LY} Diphenyliodonium chloride {} {LY} Diphenyliodonium chloride {} {} {LY} Diphenyliodonium chloride {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyliodonium chloride |
| MDL Number | MFCD00011909 |
| CAS Number | 1483-72-3 |
| PubChem Substance ID | 73870 |
| Beilstein Registry Number | 3574977 |
| EC Number | 216-049-8 |
| Merck Number | 14,7464 |
| Chemical Name Translation | 氯化二苯基碘 |
| Reaxys-RN | 3574977 |
| InChIKey | RSJLWBUYLGJOBD-UHFFFAOYSA-M |
| LabNetwork Molecule ID | LN01741799 |
| InChI | InChI=1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1 |
| Canonical SMILES | C1([I+]C2=CC=CC=C2)=CC=CC=C1.[Cl-] |
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分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 2fragments; ionic
- {SNA} Chemical Synthesis, Hypervalent Iodine, Oxidizing Agents, Synthetic Reagents
相关文献及参考
- C-Phenylation of the anions derived from malonic esters, ß-keto esters and arylacetic esters: J. Org. Chem., 28, 714 (1963). Arylation of ketones: J. Org. Chem., 31, 4315 (1966). ß-Diketones can be arylated either as monoanions: Tetrahedron, 8, 49 (1960); J. Am. Chem. Soc., 84, 2819 (1962), or as dianions: J. Org. Chem., 29, 3514 (1964), where reaction occurs at the more reactive (terminal) carbon; see, e.g. (1-phenylation of 2,4-pentanedione): Org. Synth. Coll., 6, 928 (1988). For arylation of Grignard reagents and cyanide ion, see: J. Am. Chem. Soc., 75, 2708 (1953), and of nitro-compounds: J. Org. Chem., 28, 1424 (1963); 29, 2108 (1964). Other reactions reported include: O-Phenylation of aryloxides: J. Chem. Soc., 2645 (1961), alkoxides and oximes: J. Org. Chem., 40, 3010 (1975); 36, 1780 (1971); S-Phenylation of sulfides: J. Org. Chem., 36, 233 (1971); N-Phenylation of heterocycles: Tetrahedron, 1, 145 (1957); J. Org. Chem., 39, 2710 (1974).
- For reviews of polyvalent iodine compounds in organic synthesis, see: Synthesis, 709 (1984); Chem. Rev., 96, 1123 (1996). For monographs, see: A. Varvoglis, The Organic Chemistry of Polycoordinated Iodine, VCH, N.Y. (1992); A. Varvoglis, Hypervalent Iodine in Organic Synthesis, Academic Press, San Diego (1996).
- Short: III/31b
- C-Phenylation of the anions derived from malonic esters, ß-keto esters and arylacetic esters: J. Org. Chem., 28, 714 (1963). Arylation of ketones: J. Org. Chem., 31, 4315 (1966).
- Short: EINECS
- Diphenyliodonium salts are widely used as photoinitiators for cationic polymerization: Macromolecules, 10, 1307 (1977); review: Adv. Polym. Sci., 62, 1 (1982).
- They are also useful phenylating agents for a variety of anions:
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P310+P330
- P301+P316
- P302+P352
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H301 Toxic if swallowed 吞食有毒
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R25 Toxic if swallowed 吞咽有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- MOL 文件:1483-72-3.mol
- Alfa Aesar:氯代二苯碘翁，98％ Diphenyliodonium chloride, 98+%(1483-72-3)
- 图谱信息:二苯基碘酰氯(1483-72-3)核磁图( 13 CNMR) 二苯基碘酰氯(1483-72-3)核磁图( 1 HNMR) 二苯基碘酰氯(1483-72-3)红外图谱(IR2) 二苯基碘酰氯(1483-72-3)红外图谱(IR1) 二苯基碘酰氯(1483-72-3)质谱(MS)
- TCI Shanghai:氯代二苯碘翁 Diphenyliodonium Chloride,>;98.0%(T)(1483-72-3)
- F:8
- Sigma Aldrich:1483-72-3(sigmaaldrich)
- 二苯基碘酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2356 氯代二苯碘 Diphenyliodonium Chloride 5G 623元 2014/06/02 D2356 氯代二苯碘 Diphenyliodonium Chloride 25G 1980元 2010/06/21 117330100 二苯基碘酰氯 Diphenyliodonium chloride 97% 10 GR 937元
- Acros Organics:二苯基氯化碘 Diphenyliodonium chloride, 97%(1483-72-3)
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