Chloro(1,5-Cyclooctadiene)Rhodium(I) Dimer (1,5-环辛二烯)氯铑(I)二聚体
CAS 12092-47-6 MFCD00012415
化学结构图
SMILES: C1=CCCC=CCC1.C1=CCCC=CCC1.Cl[Rh].Cl[Rh]
化学属性
| Melting Point | 243 °C (dec.)(lit.) |
|---|---|
| Solubility | Sparingly soluble in most common solvents |
| TSCA | Yes |
| Density | 1.422 |
| Mol. Formula | C16H24Cl2Rh2 |
| Mol. Weight | 493 |
| Appearance | yellow to orange xtl. |
| Stability | hygroscopic |
别名和识别编码
| Chemical Name | Chloro(1,5-Cyclooctadiene)Rhodium(I) Dimer |
|---|---|
| Synonym | 氯(1,5-环辛二烯)铑二聚 Bis(1,5-cyclooctadiene)dirhodium(I) dichloride 5-环辛二烯)铑(Ⅰ) 1,5-环辛二烯氯铑(I)二聚体 (1,5-环辛二烯)氯铑(I)二聚体 环辛二烯络氯化铑 1,5-环辛二烯氯化铑(I)二聚体 氯(1,5-环辛二烯)铑(I)二聚体 氯化铑(I) 1,5-环辛二烯络合物二聚体 1,5-环辛二烯氯铑(I)二聚体 [Rh(COD)Cl]2 二聚氯代(1,5-环辛二烯)铑(I) 双(1,5-环辛二烯氯化铑) 环辛二烯络氯化铑 Bis(1,5-cyclooctadienerhodium chloride) 二聚氯代(1,5-环辛二烯)铑(Ⅰ) 双(1,5-环辛二烯氯化铑) 5-环辛二烯)氯铑(I)二聚体 氯(1 (1 [Rh(COD)Cl]2 5-环辛二烯)铑二聚，二聚氯代(1 二聚氯代(1,5-环辛二烯)铑(I) |
| EC Number | 235-157-6 |
| PubChem Substance ID | 87563994 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | (1,5-环辛二烯)氯铑(I)二聚体 |
| Reaxys-RN | 14860700 |
| MDL Number | MFCD00012415 |
| CAS Number | 12092-47-6 |
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分类
- {SNA} 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Greener Alternative Products, Rhodium
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
- {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Rhodium
- {SNA} 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Greener Alternative Products, Rhodium Catalysts
产品应用
- 1,3-二烯和激活的烃反应的催化剂及制备手性复合物。耦合反应；不对称氢化反应； 硼氢化反应。
相关文献及参考
- Catalyzes the dehydrogenative coupling reaction of styrenes with Pinacolborane, L17558 to give the corresponding vinylboronates: Tetrahedron Lett., 40, 2585 (1999); Bull. Chem. Soc. Jpn., 75, 825 (2002). The complex has also been found to promote the atmospheric pressure carbonylation of benzylic halides to give good yields of phenylacetic acids: Tetrahedron Lett., 41, 7601 (2000).
- Homogeneous catalyst and catalyst precursor. For use in the preparation of a chiral BINAP alkene isomerization catalyst, see: Org. Synth. Coll., 8, 183 (1993).
- Miyaura has reported the Rh-catalyzed conjugate addition of arylboronic acids to ɑß-unsaturated carbonyl compounds in a single aqueous phase: Chem. Lett., 722 (2001):
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- 易吸潮。微溶于大多数普通溶剂。不溶于水。
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