N-(1-Naphthyl)Ethylenediamine Dihydrochloride N-(1-萘基)乙二胺二盐酸盐

CAS 1465-25-4 MFCD00012556

化学结构图

1465-25-4
SMILES: Cl.Cl.NCCNc1cccc2ccccc12

化学属性

Mol. FormulaC12H14N2
Mol. Weight259
Melting Point194-200
TSCAYes
SolubilitySoluble in water.
Density1.36
Stability对光、空气和湿度敏感

别名和识别编码

Chemical NameN-(1-Naphthyl)Ethylenediamine Dihydrochloride
CAS Number1465-25-4
Alfabeta NameNAPHTHALENYLETHANEDIAMINEDIHYDROCHLORIDE N1112()-----,
MDL NumberMFCD00012556
Synonym 1,2-Ethanediamine,N-1-naphthalenyl-,dihydrochloride 1-萘乙二胺二盐酸盐 2-(1-Naphthylamino)ethylamine dihydrochloride BRATTON'S REAGENT LABOTEST-BB LT00454258 N-(1-NAPHTHYL)-ETHYLENEDIAMMONIUM DICHLORIDE N-(1-NAPHTHYL)ETHYLENEDIAMINE DIHYDROCHLORIDE N-(1-Naphthyl)ethylenediamine N-(1-Naphthyl)ethylenediamine dihydrochloride N-(1-萘基)乙二胺 二盐酸盐 N-(1-萘基)乙二胺二盐酸盐 N-1-NAPHTHALENYL-1,2-ETHANEDI-AMINE DIHYDROCHLORIDE N-1-Naphthylethylene diamine dihydrochloride NCI-C03281 TIMTEC-BB SBB003095 n-(1-naphthyl)-ethylenediamindihydrochloride n-(1-napthyl)ethylenediaminedihydrochloride {} {} {Chemicalbook α-萘乙二胺盐酸
PubChem Substance ID15106
EC Number215-981-2
Beilstein Registry Number3707471
Merck Number6409
Chemical Name TranslationN-(1-萘基)乙二胺二盐酸盐
Reaxys-RN3707471
Wiswesser Line NotationL66J BM2Z &GH 2
LabNetwork Molecule IDLN00176569
InChIInChI=1S/C12H14N2.2ClH/c13-8-9-14-12-7-3-5-10-4-1-2-6-11(10)12;;/h1-7,14H,8-9,13H2;2*1H
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分类

  • {SNA} Analytical Reagents for General Use, M-N, Puriss p.a. ACS, Puriss p.a. ACS, 分析/色谱, 分析试剂
  • {SA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, M-N, Puriss p.a. ACS, Puriss p.a. ACS
  • {SNA} Amine Salts, Building Blocks, Chemical Synthesis, Nitrogen Compounds,

产品应用

  • Usually used as a coupling agent for spectrophotometric analysis.

相关文献及参考

  • Merck: 14,6409 Beilstein: 12,III,2955
  • Merck: 14,6409

安全信息

Warnings IRRITANT 危化品目录(2015) 危险化学品
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSKV5330000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
Storage condition Store at RT. Light Sensitive & Hygroscopic 充氩保存 对光线敏感，易吸潮
Hazard Codes Xn T,Xn,Xi Xi 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD691-490

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 800 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

其他信息

  • 用途一:用作测定磺胺类药物的试剂
  • F:3-8-9-23
  • Alfa Aesar:N-(1-萘)乙二胺盐酸盐,96% N-(1-Naphthyl)ethylenediamine dihydrochloride, 96%(1465-25-4)
  • MOL 文件:1465-25-4.mol
  • 图谱信息:N-(1-萘基)乙二胺二盐酸盐(1465-25-4)红外图谱(IR1) N-(1-萘基)乙二胺二盐酸盐(1465-25-4)核磁图( 1 HNMR) N-(1-萘基)乙二胺二盐酸盐(1465-25-4)质谱(MS) N-(1-萘基)乙二胺二盐酸盐(1465-25-4)红外图谱(IR2)
  • TCI Shanghai:N-(1-萘基)乙二胺二盐酸盐 N-1-Naphthylethylenediamine Dihydrochloride,>;98.0%(T)(1465-25-4)
  • 类别:有毒物品
  • 敏感性:Light Sensitive & Hygroscopic
  • 存储注意事项:光敏感
  • 用途二:环保试剂，盐酸萘乙二胺比色法测定大气中氮氧化物等苯胺类的测定，以及测定硫氨类药剂和亚硝酸盐，还可以光谱测定氨基苯酚、苯二胺、二硝基苯胺、氯苯胺、硫醇和氨磺酰等。
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 上游原料:亚硫酸氢钠 --> 乙二胺 --> a-萘酚
  • N-(1-萘基)乙二胺二盐酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A22248801 N-(1-萘基)乙二胺二盐酸盐;氢氯化萘乙二胺; 萘基盐酸二氨基乙烯; N-α-盐酸萘乙二胺; 磺胺试剂 5g 368元 2011/08/23 LA1716401 N-(1-萘基)乙二胺二盐酸盐;氢氯化萘乙二胺; 萘基盐酸二氨基乙烯; N-α-盐酸萘乙二胺; 磺胺试剂 10g 342元 2011/08/23 80088013 1-萘乙二胺二盐酸盐 10g 38.6元
  • 可燃性危险特性:受热放出有毒氯化氢和氧化氮气体
  • 检测方法:HPLC
  • Acros Organics:N-(1-萘基)乙二胺二盐酸盐 N-(1-Naphthyl)ethylenediamine, dihydrochloride, 98+%(1465-25-4)
  • 海关编码:29215990
  • 毒性分级:高毒
  • 急性毒性:腹腔-小鼠 LD50: 150 毫克/公斤
  • MSDS 信息:N-(1-Naphthyl)ethylenediamine dihydrochloride(1465-25-4).msds
  • Sigma Aldrich:1465-25-4(sigmaaldrich)
  • 灭火剂:水、二氧化碳、砂土、泡沫
  • 溶于热水，微溶于丙酮和无水乙醇。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Spectroscopy - Analytical Reagents
  4. UV/Visible (UV/VIS) Spectroscopy - 紫外/可见吸收光谱
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. ACS Grade - Inorganic Salts, Solutions and Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amine Salts - Nitrogen Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  5. M-N, Puriss p.a. ACS - Puriss p.a. ACS
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates
  1. Analytical & Chromatography 分析化学与色谱
  2. Routine Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (alphabetic sort)
  4. TLC Reagents, G-M
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Metals, precious
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Sugars
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Derivatization Reagents
  4. HPLC Derivatization Reagents, by Application
  5. Amprolium
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents HPLC
  4. HPLC Derivatization Reagents, by Application
  5. Amprolium
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (alphabetic sort)
  5. TLC Reagents, G-M
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Metals, precious
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Sugars