Bis(Triphenylphosphine)Copper(I) Borohydride 双(三苯基膦)硼氢化亚铜

CAS 16903-61-0 MFCD00013219

化学结构图

16903-61-0
SMILES: [BH4-].[Cu+].C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC36H34BCuP2
Mol. Weight603
Melting Point150
TSCANo

别名和识别编码

Chemical NameBis(Triphenylphosphine)Copper(I) Borohydride
MDL NumberMFCD00013219
PubChem Substance ID87564081
EC Number240-951-0
Synonym Bis(triphenylphosphine)copper(I) tetrahydridoborate 双(三苯基膦)硼氢化铜(I) Bis(triphenylphosphine)copper(I) borohydride
CAS Number16903-61-0
Reaxys-RN14867991
Chemical Name Translation双(三苯基膦)硼氢化亚铜
Beilstein Registry Number14867991
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分类

  • {SNA} Borohydrides, Chemical Synthesis, Reduction, Synthetic Reagents

相关文献及参考

  • Specific reagent for reduction of acid chlorides to aldehydes: Tetrahedron Lett., 1437 (1978); 975 (1979). Also reduces sulfonylhydrazones to alkanes: Tetrahedron Lett., 4031 (1980), and aryl azides to amines: J. Chem. Res. (Synop.), 17 (1981).
  • In the presence of Lewis acids or HCl, reduces carbonyl compounds with good stereo- and chemo-selectivity, e.g. aldehydes in the presence of ketones: Tetrahedron Lett., 22, 675 (1981).

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S8 Keep container dry 保持容器干燥；
Packing GroupIII
UN Number 2813 UN2813
Risk Statements
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P405 Store locked up. 上锁保管。
  • P501a
GHS Symbol
Hazard Codes 4.3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Borohydrides - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Borohydrides - Reduction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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