DI-Tert-Butyl Hydrazodicarboxylate 二叔丁基叠氮草酸

CAS 16466-61-8 MFCD00015000

化学结构图

16466-61-8
SMILES: CC(C)(C)OC(=O)NNC(=O)OC(C)(C)C

化学属性

Mol. FormulaC10H20N2O4
Mol. Weight232
Melting Point123-126
TSCANo

别名和识别编码

Chemical NameDI-Tert-Butyl Hydrazodicarboxylate
Synonym 二叔丁基叠氮草酸 N,N'-Di-tert-butoxycarbonylhydrazineDi-tert-butyl hydrazodiformate 叠氮草酸二叔丁酯 N,N'-Di-tert-butoxycarbonylhydrazine 叠氮二羧酸二叔丁酯
MDL NumberMFCD00015000
PubChem Substance ID160871276
CAS Number16466-61-8
EC Number240-512-3
Beilstein Registry Number1794023
Chemical Name Translation二叔丁基叠氮草酸
Reaxys-RN1794023
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks
  • Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks

相关文献及参考

  • Beil. 3 ,IV,176
  • IR-Spectra (3), 454:B / IR-Spectra (2), 401:F / NMR-Reference 2 (1), 653:B
  • Effective catalyst, in combination with CuCl : phenanthroline, for the aerobic oxidation of a variety of alcohols, aliphatic primary or secondary, benzylic or allylic to aldehydes or ketones. The method has potential as an ecologically benign process, since water is the only by-product: J. Org. Chem., 64, 2433 (1999):
  • Effective catalyst, in combination with CuCl : phenanthroline, for the aerobic oxidation of a variety of alcohols, aliphatic primary or secondary, benzylic or allylic to aldehydes or ketones. The method has potential as an ecologically benign process, since water is the only by-product: J. Org. Chem., 64, 2433 (1999):

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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