N-Methyl-O-Toluidine N-甲基-邻甲基苯胺

CAS 611-21-2 MFCD00025627

化学结构图

611-21-2
SMILES: CNc1ccccc1C

化学属性

Mol. FormulaC8H11N
Mol. Weight121.18
Density0.981 g/mL at 25 °C(lit.)
Boiling Point207.5°C at 760 mmHg
Refractive index1.5630 to 1.5660
Flash Point79°C(lit.)
Appearance 浅黄色油状液体。熔点119.5℃，沸点209-210℃。
Melting Point-10.08 °C

别名和识别编码

Chemical NameN-Methyl-O-Toluidine
CAS Number611-21-2
Alfabeta NameDIMETHYLANILINE N2-,
MDL NumberMFCD00025627
Synonym N,2-Dimethylaniline {LY} N,2-Dimethylaniline {} {LY} N,2-Dimethylaniline {} {} {LY} N,2-Dimethylaniline {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,2-Dimethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID69137
EC Number210-260-9
Reaxys-RN742175
Beilstein Registry Number12(3)1842
Chemical Name TranslationN-甲基-邻甲基苯胺
LabNetwork Molecule IDLN00159551
InChIInChI=1S/C8H11N/c1-7-5-3-4-6-8(7)9-2/h3-6,9H,1-2H3
Canonical SMILESCC1=CC=CC=C1NC
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C8, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT
WGK Germany3
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P310
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P302+P350
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P311
Signal word Danger
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes T
Risk Statements
  • R52/53
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R33 Danger of cumulative effects 有累积作用的危险
UN Number 2810 1711
Packing GroupIII
Hazard Class6.1
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 用途一:用于有机合成
  • MOL 文件:611-21-2.mol
  • 图谱信息:N-甲基-邻甲基苯胺(611-21-2)核磁图( 13 CNMR) N-甲基-邻甲基苯胺(611-21-2)红外图谱(IR2) N-甲基-邻甲基苯胺(611-21-2)质谱(MS) N-甲基-邻甲基苯胺(611-21-2)核磁图( 1 HNMR) N-甲基-邻甲基苯胺(611-21-2)红外图谱(IR1)
  • N-甲基-邻甲基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0445 N-甲基邻甲苯胺 N-Methyl-o-toluidine 25ML 1180元 2010/06/21 345740050 N-甲基-邻甲基苯胺 N-Methyl-o-toluidine 98% 5 GR 1225元 2010/06/21 345740250 N-甲基-邻甲基苯胺 N-Methyl-o-toluidine 98% 25 GR 3855元
  • TCI Shanghai:N-甲基邻甲苯胺 N-Methyl-o-toluidine,>;95.0%(GC)(611-21-2)
  • Sigma Aldrich:611-21-2(sigmaaldrich)
  • 存储注意事项:空气敏感
  • 上游原料:四氢呋喃 --> 正己烷 --> 甲醛 --> 硼氢化钠 --> 邻甲基苯胺 --> 苯骈三氮唑
  • Acros Organics:N-甲基-邻甲苯胺 N-Methyl-o-toluidine, 98%(611-21-2)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. pH Buffers for Titration - Titration
  5. Buffer Solutions - pH Buffers for Titration
  6. Buffer Solutions, pH 1 - 4 - Buffer Solutions
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. C12 - Amines
  1. C8 - Amines

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