Ethyltriphenylphosphonium iodide 乙基三苯基碘化鏻

CAS 4736-60-1 MFCD00040352

化学结构图

4736-60-1
SMILES: CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[I-]

化学属性

Mol. FormulaC20H20IP
Mol. Weight418.26
Melting Point164-168°C
TSCAYes
Flash Point226 ºC
Boiling Point337 °C at 760 mmHg
Solubility略溶于水
Density1.0
Stability对光线和湿度敏感
Appearance 白色至类白色晶体，熔点164-170℃

别名和识别编码

Chemical NameEthyltriphenylphosphonium Iodide
CAS Number4736-60-1
Synonym Ethyltriphenylphosphonium iodide {LY} Ethyltriphenylphosphonium iodide {} {LY} Ethyltriphenylphosphonium iodide {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {}
PubChem Substance ID78474
EC Number225-245-2
Beilstein Registry Number3659323
MDL NumberMFCD00040352
Reaxys-RN3659323
Chemical Name Translation乙基三苯基碘化鏻
Wiswesser Line Notation2PR&R&R &I
LabNetwork Molecule IDLN00198290
InChIInChI=1S/C20H20P.HI/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h3-17H,2H2,1H3;1H/q+1;/p-1
Canonical SMILESCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[I-]
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Phase Transfer Catalysts, Phosphonium Salts, Synthetic Reagents, Wittig Reagents
  • Wittig Reagents
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

产品应用

  • Wittig reagent.

相关文献及参考

  • Beilstein:16(2)373
  • The phosphorane, generated by reaction with n-BuLi, reacts with nitriles to give high yields of ketones: J. Am. Chem. Soc., 89, 7009 (1967).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H300 Fatal if swallowed 吞食致命
  • H301 Toxic if swallowed 吞食有毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes 6.1 T
RTECSTA2312000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P316
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 3464 UN 2811 6.1/PG 3
Safety Statements
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R25 Toxic if swallowed 吞咽有毒
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room te
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#05926

其他信息

  • F:3-8-10
  • 海关编码:29310095
  • 三苯基乙基碘化价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0549 乙基三苯基碘化 Ethyltriphenylphosphonium Iodide 25G 266元 2014/06/02 E0549 乙基三苯基碘化 Ethyltriphenylphosphonium Iodide 250G 1260元 2010/06/21 309191000 三苯基乙基碘化 Ethyltriphenylphosphonium iodide 95% 100 GR 695元
  • 图谱信息:三苯基乙基碘化(4736-60-1)核磁图( 13 CNMR) 三苯基乙基碘化(4736-60-1)核磁图( 1 HNMR) 三苯基乙基碘化(4736-60-1)质谱(MS)
  • Alfa Aesar:碘化乙基三苯基瞵,98+% Ethyltriphenylphosphonium iodide, 98+%(4736-60-1)
  • Sigma Aldrich:4736-60-1(sigmaaldrich)
  • MSDS 信息:Ethyltriphenylphosphonium iodide(4736-60-1).msds
  • Acros Organics:碘化乙基三苯鏻 Ethyltriphenylphosphonium iodide, 95%(4736-60-1)
  • 微溶于水。
  • 敏感性:Light Sensitive & Hygroscopic
  • TCI Shanghai:乙基三苯基碘化磷 Ethyltriphenylphosphonium Iodide(4736-60-1)
  • MOL 文件:4736-60-1.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Phosphonium Salts - Phase Transfer Catalysts
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Others - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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