Triphenyl((2-(Trimethylsilyl)Ethoxy)Methyl)Phosphonium Chloride ((2-(三甲基硅烷基)乙氧基)甲基)三苯基氯化鏻

CAS 82495-75-8 MFCD00043159

化学结构图

82495-75-8
SMILES: [Cl-].C[Si](C)(C)CCOC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC24H30ClOPSi
Mol. Weight429.01
Melting Point145-149 °C(lit.)

别名和识别编码

Chemical NameTriphenyl((2-(Trimethylsilyl)Ethoxy)Methyl)Phosphonium Chloride
Synonym SEM-三苯基氯化磷 2-(三甲基硅烷)乙氧三苯甲基氯化膦
Beilstein Registry Number4632507
PubChem Substance ID87577220
CAS Number82495-75-8
MDL NumberMFCD00043159
Reaxys-RN4632507
Chemical Name Translation((2-(三甲基硅烷基)乙氧基)甲基)三苯基氯化鏻
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分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Becker, M. H.; et al. J. Am. Chem. Soc. 129 , 11987, (2007)
  • 2. Lindenschmidt, A. Sci. Synth. 25 , 237, (2007)
  • 3. Kuba, M.; et al. Chem. Lett. , 1248, (2002)
  • 4. Muller, P.; et al. Tetrahedron Asymmetry 13 , 551, (2002)
  • FT-IR 2 (3), 4431:D / FT-NMR 1 (3), 712:C / RegBook 1 (2), 3003:J / Structure Index 1 , 476:D:3

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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