(R)-α-Methoxy-α-(Trifluoromethyl)Phenylacetyl Chloride (R)-α-甲氧基-α-(三氟甲基)苯乙酰氯

CAS 39637-99-5 MFCD00044400

化学结构图

39637-99-5
SMILES: CO[C@](C(=O)Cl)(c1ccccc1)C(F)(F)F

化学属性

Mol. FormulaC10
Mol. Weight253
Boiling Point213-214
Refractive index1.4680 to 1.4710
Density1.35
Flash Point89°C(lit.)
TSCANo

别名和识别编码

Chemical Name(R)-α-Methoxy-α-(Trifluoromethyl)Phenylacetyl Chloride
CAS Number39637-99-5
Alfabeta NameMETHOXYTRIFLUOROMETHYLPHENYLACETYLCHLORIDE ALPHAALPHAR(())-------
MDL NumberMFCD00044400
Synonym (R)-(-)-α-甲氧基-α-(三氟甲基)苯乙酰氯 (R)-(-)-Mosher's acid chloride
PubChem Substance ID160871318
Beilstein Registry Number359156
Merck Number6280
Reaxys-RN3561563
Chemical Name Translation(R)-α-甲氧基-α-(三氟甲基)苯乙酰氯
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分类

  • {SNA} Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC

产品应用

  • 用于测定乙醇和胺类的纯度。

相关文献及参考

  • Chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines by NMR: J. Am. Chem. Soc., 95, 512 (1973).
  • Merck: 14,6280

安全信息

Warnings MOISTURE SENSITIVE, KEEP COLD, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P403+P233
  • P305+P351+P338+P310
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P301+P330+P331+P310
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P303+P361+P353
  • P304+P340+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P308+P311
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
Signal word
Packing GroupIII
UN Number UN3265 3265
Risk Statements
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Storage condition Moisture Sensitive 0-10 0-10°C 储存温度:-20°C,干冰运输
Hazard Codes C
Hazard Class8

系列性分类


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