Ammonium hydroxide 氨水

CAS 1336-21-6 MFCD00066650

化学结构图

1336-21-6
SMILES: [NH4+].[OH-]

化学属性

Mol. FormulaH5NO
Mol. Weight35.05
Density0.89
TSCAYes
Melting Point-57
Boiling Point-
Autoignition Point1204 °F
Vapor Density1.2 (vs air)
Vapor Pressure115 mmHg ( 20 °C)
Solubility溶于水、醇。
Stability对二氧化碳敏感
Flash Point-

别名和识别编码

Chemical NameAmmonium hydroxide
Synonym Ammonium hydroxide {LY} Ammonium hydroxide {} {LY} Ammonium hydroxide {} {} {LY} Ammonium hydroxide {} {} {} {LY} Ammonium hydroxide {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium hydroxide {} {} {} {} {}
CAS Number1336-21-6
PubChem Substance ID57649967
EC Number215-647-6
Beilstein Registry Number3587154
MDL Number-
Merck Number14,494
Chemical Name Translation氨水
Reaxys-RN3587154
InChIKeyVHUUQVKOLVNVRT-UHFFFAOYSA-N
Wiswesser Line NotationZ& Q
LabNetwork Molecule IDLN00196016
Canonical SMILES[NH4+].[OH-]
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分类

  • {SNA} Analytical R
  • {SNA} Analytical Reagents, Analytical/Chromatography, Atomic Absorption Spectroscopy (AAS), Digestion Reagents, High Purity Bases for Trace Analysis (TRACESELECT), Pure Reagents for Wet Digestion (TraceSELECT), Reagents for Inorganic Trace Analysis, Spectroscopy, Trace Analysis Reagents & Solvents
  • {SNA} Chromatography Reagents & Solvents,
  • {SNA} Analytical Reagents, Analytical/Chromatography,
  • {SNA}

产品应用

  • 分析试剂,中和剂,生物碱浸出剂。用于某些元素(如铜、镍)的检定和测定。用以沉淀出各种元素的氢氧化物。制备铵化合物,洗涤剂,比色测定。

相关文献及参考

  • Merck: 14,494
  • Short: II/5
  • Short: EINECS2
  • Short: IV/4
  • Short: IV/1b

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, Gloves, Goggles Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C,N N
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
RTECSBQ9625000
Safety Statements
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
UN Number 2672 UN 2672 8/PG 3 UN2672
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
  • R50 Very toxic to aquatic organisms 对水生生物极毒
Packing GroupIII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class8
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 91 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - coma
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   JCINAO Journal of Clinical Investigation.  (Rockefeller Univ. Press, 1230
   York Ave., New York, NY 10021)  V.1-    1924-  Volume(issue)/page/year:
   37,497,1958

TYPE OF TEST            : TCLo - Low

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 408 ppm
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - fibrosis, focal (pneumoconiosis)
   Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
   JISMAB Journal of the Iowa State Medical Society.  (Des Moines, IA)
   1911-1983(?).  Volume(issue)/page/year: 61,271,1971

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 5000 ppm
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,95,1969

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85IXA4 "Structure et Activite Pharmacodyanmique des Medicaments du Systeme
   Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948
    Volume(issue)/page/year: -,688,

{hazard_com

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 mg/disc
REFERENCE :
   ANYAA9 Annals of the New York Academy of Sciences.  (New York Academy of
   Sciences, 2 E. 63rd St., New York, NY 10021)  V.1-    1877-
   Volume(issue)/page/year: 76,475,1958

Restrict 危险品

其他信息

  • MOL 文件:1336-21-6.mol
  • 1.将本品垂直放于1升的容量瓶上。
  • 毒性分级:中毒
  • 下游产品:安果 --> 肾上腺素 --> 2-氨基-3-吡啶甲醛盐酸盐 --> (1-甲基-1H-苯并眯唑-2-基)甲胺 --> 2-氯-6-甲基嘧啶-4-胺 --> 3-氨基-4,4,4-三氟巴豆酸乙酯 --> 2,4-二甲基咪唑 --> 6-溴-2-吡啶-氨基甲酸-1,1-二甲基乙基酯 --> 美索巴莫 --> 2-蒽甲酸 --> 糖精铵 --> 硫酸新霉素 --> 异帕米星 --> 2-萘胺-3,6,8-三磺酸 --> 草酸高铁铵 --> 2,4-二氯苯腈 --> 3-氨基-6-氯哒嗪 --> 磷钼酸铵 --> 8-羟基-5-甲基喹啉 --> 直接蓝 199 --> 合成增稠剂 KG-201 --> 草铵膦 --> 仲辛基酚聚乙烯(15)醚 --> 谷氨酸一铵 --> N,1,5-三甲基-1H-吡唑-3-甲酰胺 --> 4-硝基苯磺酰胺 --> 四氰金酸钾 --> 强力霉素一水物 --> 1
  • 为氨的水溶液。氨含量越多,密度越小。易挥发逸出氨气,有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒,半数致死量(大鼠,经口)352mg/kg。有腐蚀性。催泪性。
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) 氨水 食品 食品工业用加工助剂 / 食品工业用加工助剂一般应在制成最后成品之前出去,有规定食品中残留量的除外
  • 上游原料:氢氧化钠 --> 盐酸 --> 甲醇 --> 氯化钠 --> 氨
  • 类别:压缩气体和液化气体
  • 氢氧化铵价格(试
  • F:34
  • 为氨的水溶液。氨含量越多,密度越小。易挥发逸出氨气,有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒,半数致死量(大鼠,经口)350mg/kg。有腐蚀性。催泪性。
  • 刺激数据:眼睛-兔子
  • 为氨的水溶液。氨含量越多,密度越小。易挥发逸出氨气,有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒,半数致死量(大鼠,经口)353mg/kg。有腐蚀性。催泪性。
  • 每瓶安瓿可稀释成一升的滴定液
  • 用途二:用作分析试剂,铝盐合成和弱碱性溶剂
  • 灭火剂:水
  • 为氨的水溶液
  • 2.用附带的小工具从上至下刺破薄膜,使浓缩液流入容量瓶中
  • 急性毒性:口服-大鼠 LD50: 350 毫克/公斤; 吸入-人 TCL0: 408 PPM
  • 为氨的水溶液。氨含量越多,密度越小。易挥发逸出
  • 为氨的水溶液。氨含量越多,密度越小。易挥发逸出氨气,有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒,半数致死量(大鼠,经口)356mg/kg。有腐蚀性。催泪性。
  • Acros Organics:氨水 Ammonium hydroxide, 25% solution in water, for analysis(1336-21-6)
  • {Chemicalbook
  • 用途三:用于制药
  • MSDS 信息:氨溶液(1336-21-6).msds
  • 可燃性危险特性:遇热放出有毒可燃氨气; 与活泼金属反应生成易燃氢气; 火场放出氮氧化物烟雾
  • 为氨的水溶液。氨含量越多,密度越小。易挥发逸出氨气,有强烈的刺激性气味。能与乙醇混溶。呈强碱
  • 为氨的水溶液。氨含量越多,密度越小。易挥发逸出氨气,有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒,半数致死量(大鼠,经口)357mg/kg。有腐蚀性。催泪性。

系列性分类


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