(S)-3,3,3-Trifluoro-2-Methoxy-2-Phenylpropanoyl Chloride (S)-3,3,3-三氟-2-甲氧基-2-苯基丙酰氯

CAS 20445-33-4 MFCD00067105

化学结构图

20445-33-4
SMILES: CO[C@@](C(=O)Cl)(c1ccccc1)C(F)(F)F

化学属性

Mol. FormulaC10H8ClF3O2
Mol. Weight253
Boiling Point68-72
Refractive index1.4670 to 1.4700
Density1.35
Flash Point89°C(lit.)
TSCANo

别名和识别编码

Chemical Name(S)-3,3,3-Trifluoro-2-Methoxy-2-Phenylpropanoyl Chloride
CAS Number20445-33-4
Alfabeta NameMETHOXYTRIFLUOROMETHYLPHENYLACETYLCHLORIDE ALPHAALPHAS+(())------
MDL NumberMFCD00067105
Synonym (S)-(+)-ALPHA-METHOXY-ALPHA-(TRIFLUOROMETHYL)BENZENEACETYLCHLORIDE (S)-(+)-MTPA-Cl (S)-(+)-MTPA-Cl Mosher 酸氯化物 (+)-ALPHA-METHOXY-ALPHA-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (R)-(-)-A-METHOXY-A-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (S)-(+)-Mosher's acid chloride R(-)-MTPA-CL (+)-MTPA-CL (R)-(-)-ALPHA-METHOXY-ALPHA-(TRIFLUOROMETHYL)BENZENEACETYLCHLORIDE Mosher 酸氯化物 (S)-(+)-1-METHOXY-1-(TRIFLUOROMETHYL)PHENYL ACETYL CHLORIDE (S)-(+)-MTPA-CL MOSHER'S ACID CHLORIDE (S)-(-)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETYL CHLORIDE (S)-(+)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETYL CHLORIDE (R)-(+)-1-METHOXY-1-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (S)-(+)-A-METHOXY-A-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (S)-(+)-α-甲氧基-α-三氟甲基苯乙酰氯 R(-)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID CHLORIDE (+)-MOSHER'S ACID CHLORIDE (R)-(-)-1-METHOXY-1-(TRIFLUOROMETHYL)PHENYL ACETYL CHLORIDE (S)-(+)-α-Methoxy-α-trifluoromethylphenylacetyl chloride (R)-(-)-ALPHA-METHOXY-ALPHA-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (+)-MOSHER'S CHLORIDE (+)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetylChloride[forDeterminationoftheopticalpurityofAlcoholsandAmines]
PubChem Substance ID160871159
Beilstein Registry Number3591562
Reaxys-RN3591562
Merck Number6280
Chemical Name Translation(S)-3,3,3-三氟-2-甲氧基-2-苯基丙酰氯
InChIKeyPAORVUMOXXAMPL-VIFPVBQESA-N
LabNetwork Molecule IDLN00118763
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分类

  • Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks
  • {SNA} Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC

相关文献及参考

  • 1. Angew. Chem. Int. Ed. Engl. 43 , 2420-2423, (2004) 摘要
  • 2. Org. Lett. 6 , 1757-1760, (2004) 摘要
  • 3. J. Chem. Ecol. 30 , 819-834, (2004) 摘要
  • Hoye, T. R.; Jeffrey, C. S.; Shao, F. Nat. Protoc. 2 , 2451-2458, (2007) 摘要
  • Merck 14 ,6280
  • FT-NMR 1 (2), 1333:C / RegBook 1 (2), 1965:I / Structure Index 1 , 316:C:2

安全信息

Warnings MOISTURE SENSITIVE, KEEP COLD, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Storage condition Moisture Sensitive 0-10 0-10°C -20°C
UN Number 3265 UN3265
Risk Statements
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
Hazard Class8

其他信息

  • Sigma Aldrich:20445-33-4(sigmaaldrich)
  • F:10-21

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Chiral Derivatization Reagents - Derivatization Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents HPLC - Derivatization Reagents
  5. Chiral - Derivatization Reagents HPLC
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Acid Halides 酰卤
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Acid Halides 酰卤
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Derivatization Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Chiral Derivatization
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents HPLC
  1. Acyl halide
  2. acyl chloride

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