Boron trifluoride methanol complex solution 三氟化硼甲醇络合物

CAS 2802-68-8 MFCD00071635

化学结构图

2802-68-8
SMILES:

化学属性

Mol. FormulaCH4BF3O
Mol. Weight99.85
Density0.859 g/mL at 25 °C
Flash Point29°C(lit.)
TSCAYes
Boiling Point59
Refractive index1.34
Autoignition Point788 °F
Vapor Pressure19.5 mmHg ( 20 °C)
Melting Point-20
Stability对湿度敏感
Solubility水解

别名和识别编码

Chemical NameBoron trifluoride methanol complex solution
CAS Number2802-68-8
Reaxys-RN3611499
Merck Number1349
MDL NumberMFCD00071635
PubChem Substance ID87563865
Beilstein Registry Number3693581
EC Number220-543-9
Synonym Boron trifluoride methanol complex,14 wt. % solution in MeOH,Safeseal {LY} Boron trifluoride methanol complex,14 wt. % solution in MeOH,Safeseal Boron trifluoride-dimethanol complex, 50-52% w/w boron trifluoride Boron trifluoride-methanol in methanol Boron trifluoride-methanol in methanol (ca. 50% w/w boron trifluoride) Boron trifluoride-methanol-complex solution Hydrogen trifluoromethoxyborate, compound with methanol Hydrogentrifluoromethoxyborate(1-),compoundwithmethanol(1:1) Methanol-boron trifluoride complex (2:1) Trifluoroborane {} {LY} Boron trifluoride methanol complex,14 wt. % solution in MeOH,Safeseal {} {} {LY} Boron trifluoride methanol complex,14 wt. % solution in MeOH,Safeseal {} {} {} {LY} Boron trifluoride methanol complex,14 wt. % solution in MeOH,Safeseal {} {} {} {} {LY} Boron trifluoride methanol complex,14 wt. % solution in MeOH,Safeseal
Chemical Name Translation三氟化硼甲醇络合物
InChIKeyWWNADQBMJRRNDS-UHFFFAOYSA-L
Chemicalbook IDCB6501776
LabNetwork Molecule IDLN00162977
InChIInChI=1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;
Canonical SMILESFB(F)F.CO
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分类

  • {SNA} Acids, Acids & Bases, Boron, Boron Catalysts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Synthetic Reagents
  • {SNA} Boron,
  • {SNA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Acylation, Reagents for Alkylation & Esterification
  • {SNA} 25mL Sure/Seal Reagents, Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Organometallic Reagents, Synthetic Reagents
  • {SNA} Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis, Electronic Chemicals, Fluor

相关文献及参考

  • Beil. 1 ,IV,1220
  • Fieser 1 ,73 / Fieser 9 ,64
  • Aldrich MSDS 1 , 220:C / Corp MSDS 1 (1), 484:A / Corp MSDS 1 (1), 484:B / Sigma FT-IR 1 (2), 1017:B / Structure Index 1 , 479:A:8
  • Reagent for esterification of acids: J. Chem. Soc., 5770 (1965); and also for the selective cleavage of trityl ethers: Carbohydr. Res., 65, 132 (1978).

安全信息

UN Number 2920 2924
Signal word
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H370 Causes damage to organs 导致器官损伤
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301+H311+H331
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P403+P233
  • P305+P351+P338+P310
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P308+P311
  • P241+P242+P243
  • P303+P361+P353+P310+P363
GHS Symbol
WGK Germany1
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,T F,T+ T,T+,F
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
Packing GroupII
Risk Statements
  • R11 Highly flammable 非常易燃
  • R26 Very toxic by inhalation 吸入极毒
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R48/23
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R35 Causes severe burns 会导致严重灼伤
  • R34 Causes burns 会导致灼伤
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R14 Reacts violently with water 遇水会猛烈反应
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {ALF} Moist
Hazard Class8/3

其他信息

  • PackingGroup:II
  • HazardClass:8
  • EPA化学物质信息:Borate(1-), trifluoromethoxy-, (T-4)-, hydrogen, compd. with methanol (1:1)(2802-68-8)
  • 敏感性:Moisture Sensitive
  • 三氟化硼甲醇络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0894 三氟化硼-甲醇络合物 Boron Trifluoride - Methanol Complex 500ML 837元 2014/06/02 B0894 三氟化硼-甲醇络合物 Boron Trifluoride - Methanol Complex 100ML 292元 2010/06/21 158900500 三氟化硼甲醇络合物 Boron trifluoride dimethanol complex , 50-52 wt% BF3 50 GR 399元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Boron 硼
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Seal™ Reagents 专有包装技术有机金属
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Acylation - Derivatization Reagents GC
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Alkylation & Esterification - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  4. Boron - Lewis Acids
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Electronic Chemicals - Micro/NanoElectronics
  4. Fluorides - Electronic Chemicals
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物

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