Chloromethyl Chloroformate 氯甲酸氯甲酯
CAS 22128-62-7 MFCD00077688
化学结构图
SMILES: O=C(Cl)OCCl
化学属性
| Mol. Formula | ClCOOCH2Cl |
|---|---|
| Mol. Weight | 128.94 |
| Refractive index | n20/D 1.428 |
| Boiling Point | 107-108 °C(lit.) |
| Density | 1.450 g/mL at 20 °C |
| Flash Point | 95°(203°F) |
| TSCA | No |
| Melting Point | <-20° |
别名和识别编码
| Chemical Name | Chloromethyl Chloroformate |
|---|---|
| Synonym | Chlorameisensäure-chlormethylester Chloromethoxycarbonyl chloride Chlormethylchlorformiat Carbonochloridic acid, chloromethyl ester CHLOROMETHYL CHLOROFORMATE (JMC)(INTERMEDIATE OF TENOFOVIR DISOPROXIL FUMARATE) chloromethyl carbonochloridate Formic acid, chloro-, chloromethyl ester chlorocarbonic acid chloromethyl ester CHLOROMETHYL CHLOROFORMATE 氯甲酸氯甲酯 N(Α)-苄氧羰基-L-赖氨酸 Carbonochloridic acid chloromethyl ester Chloromethylchloroformate chloromethyl chloroformate CMCF JMC Chloroformic acid chloromethyl ester chlorocarbonicacidchloromethylester Chlorameisensäurechlormethylester Chloromethylchloroformate,97% 氯仿酸氯甲酯 CHLOROFORMIC ACID CHLOROMETHYL ESTER Chloromethyl Chloroformate (JMC) |
| PubChem Substance ID | 57648023 |
| EC Number | 244-793-3 |
| Beilstein Registry Number | 506426 |
| MDL Number | MFCD00077688 |
| CAS Number | 22128-62-7 |
| Chemical Name Translation | 氯甲酸氯甲酯 |
| InChIKey | JYWJULGYGOLCGW-UHFFFAOYSA-N |
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分类
- {SNA} Acid Halides, Analytical Reagents, Analytical/Chromatography, Building Blocks, Carbonyl Chlorides, Carbonyl Compounds, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents HPLC, Fluorescence, Halogenated, Organic Building Blocks
- {uni_hamburg} no charge; carbonyl chloride; 1fragment
- {SNA} Acid Halides, Building Blocks, Carbonyl Chlorides, Carbonyl Compounds, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents HPLC, Fluorescence, Halogenated, Organic Building Blocks, 分析/色谱, 分析试剂
相关文献及参考
- Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
- Short: III/39 Title: Nuclear Quadrupole Resonance Spectroscopy Data Author: Chihara, H.; Nakamura, N. Editor: Chihara, H. Source: Landolt-Börnstein, New Series Volume: III/39 Year: 1997 Keyword: NQR; spectroscopy ISBN: 3-540-62428-7 ISBN: 978-3-540-62428-8 Internet Resource: DOI:10.1007/b61951 RefComment: VIII, 424 pages. H
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H331 Toxic if inhaled 吸入中毒
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- R34 Causes burns 会导致灼伤
- R14 Reacts violently with water 遇水会猛烈反应
- R22 Harmful if swallowed 吞咽有害
- R23 Toxic by inhalation 吸入有毒
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
其他信息
- MSDS 信息:氯甲酸氯甲酯(22128-62-7).msds
- 外观性质:有渗透性、刺激性的无色液体, 易分解。
- 毒性分级:高毒
- Sigma Aldrich:22128-62-7(sigmaaldrich)
- Alfa Aesar:氯仿酸氯甲酯,97% Chloromethyl chloroformate, 97%(22128-62-7)
- 急性毒性:吸入-小鼠 TDL0: 344 毫克/立方米; 口服-大鼠 LD50: <; 50 毫克/公斤
- 储运特性:库房通风低温干燥; 与氧化剂, 食品分开储运
- F:10-19-21
- 用途一:用作医药、农药的中间体
- MOL 文件:22128-62-7.mol
- 灭火剂:干粉, 砂土, 泡沫, 二氧化碳
- 敏感性:Moisture Sensitive
- 可燃性危险特性:遇水, 或受热放出有毒氯化氢气体
- 类别:有毒物品
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