(+)-Bornyl acetate (-)-乙酸冰片酯

CAS 5655-61-8 MFCD00135942

化学结构图

5655-61-8
SMILES: CC(=O)OC1CC2CCC1(C)C2(C)C

化学属性

Mol. FormulaC12H20O2
Mol. Weight196.29
Density0.986
Refractive indexn20/D 1.463(lit.)
Flash Point84°C(lit.)
TSCAYes
Boiling Point223-224
Appearance 无色液体，室温下固化。熔点27.7℃，沸点225-226℃，98℃（1.33kPa），相对密度0.991（25/25℃），折光率1.4639，闪点84℃。微溶于水，易溶于酒精、乙醚。具有森林的新鲜香气。天然含于针叶油中，特别在冷杉油中为多。
Vapor Pressure0.6 mmHg ( 20 °C)

别名和识别编码

Chemical Name(+)-Bornyl acetate
MDL NumberMFCD00867808
EC Number227-101-4
CAS Number5655-61-8
Merck Number1339
Beilstein Registry Number2502036
Synonym (+)-BORNYL ACETATE (-)-BORNYL ACETATE (-)-Bornyl acetate {Chemicalbook} (1S,2R,4S)-bornyl acetate (1S-内型)-7,7-三甲基二环[2.2.1]庚烷-2-醇乙酸酯 1,7,7-trimethyl-,acetate,(1S-endo)-Bicyclo[2.2.1]heptan-2-ol 1-乙酸冰片酯 1-乙酸冰片酯/乙酸龙脑脂 BORNYL ACETATE, L- Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,acetate,(1S-endo)- Borneol, acetate, (1S,2R,4S)-(-)- Bornyl acetate,endo-(1S)-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl acetate ENDO-(1R)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPT-2-YL-ACETATE ENDO-(1S)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPT-2-YL ACETATE FEMA 2159 L-(-)-乙酸龙脑酯 L-born-2-yl acetate Levo-bornyl acetate bornyl acetate {} {Chemicalbook {} {SNA} (-)-乙酸冰片酯 {} {} {} {} {} {} {} {C 乙酸龙脑脂 内型-(1S)-1,7,7-三甲基二环[2.2.1
PubChem Substance ID93009
Chemical Name Translation(-)-乙酸冰片酯
Reaxys-RN1909308
LabNetwork Molecule IDLN04630163
InChIInChI=1S/C12H20O2/c1-8(13)14-10-7-9-5-6-12(10,4)11(9,2)3/h9-10H,5-7H2,1-4H3/t9-,10+,12+/m0/s1
Canonical SMILESCC1(C)[C@@]2(C)[C@H](OC(C)=O)C[C@]1([H])CC2
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Asymmetric Synthesis, B, BI - BZ, Chemical Class, Chemical Synthesis, Chiral Building Blocks, Chromatography, Esters, Life Sciences Standards, Natural Compounds, Organic Building Blocks
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Asymmetric Synthesis, B, BI - BZ, Chemical Class, Chemical Synthesis, Chiral Building Blocks, Chromatography,
  • {SNA} Addit
  • {SNA} Asymmetric Synthesis, Boswellia

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+P378
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H227 Combustible liquid 可燃液体
Storage condition 2-8°C

其他信息

  • Alfa Aesar:L-(-)-乙酸龙脑酯,95% L-(-)-Bornyl acetate, 95%(5655-61-8)
  • 用途一:广泛用于肥皂、化妆品以及室内消毒杀菌的芳香清洁剂。是室内喷雾香精、浴用香精、爽身粉的重要组分。少量用于食品香料。
  • 方法一:可从冷杉油中蒸馏分离而得；工业上合成方法是将龙脑与乙酸在乙酸钠存在下加热而得。纯度98%以上。
  • MOL 文件:5655-61-8.mol
  • Acros Organics:1-乙酸冰片酯/乙酸龙脑脂 L-Bornyl acetate, 95%(5655-61-8)
  • TCI Shanghai:乙酸龙脑酯(含约20%的乙酸异龙脑酯) Bornyl Acetate (contains ca. 20% Isobornyl Acetate),>;70.0%(GC)(5655-61-8)
  • Sigma Aldrich:5655-61-8(sigmaaldrich)
  • 蒸气压:0.6 mm Hg ( 20 °C)
  • 上游原料:(1S,4R,6R)-1,7,7-三甲基二环[2.2.1]庚-6-醇 --> 冷杉油

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. F - Alphabetic
  5. FA - FL - F
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BI - BZ - B
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Life Sciences Standards - Chromatography
  5. Natural Compounds - Life Sciences Standards
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. E - Alphabetic
  5. EA - EO - E
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Protected Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Polyols 多元醇
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Terpenes

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