Methanesulfonic acid, 1,1,1-trifluoro-, indium(3+) salt (3:1) 三氟甲磺酸铟
CAS 128008-30-0 MFCD00144478
化学结构图
SMILES: O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.[In+3]
化学属性
| TSCA | No |
|---|---|
| Mol. Formula | C3F9InO9S3 |
| Mol. Weight | 562 |
| Appearance | white pwdr. |
| Stability | hygroscopic |
| Melting Point | dec. |
别名和识别编码
| Chemical Name | Methanesulfonic acid, 1,1,1-trifluoro-, indium(3+) salt (3:1) |
|---|---|
| Synonym | INDIUM TRIFLATE INDIUM TRIFLUOROMETHANESULFONATE INDIUM TRIFLUOROMETHANESULPHONATE INDIUM(III) TRIFLATE INDIUM(III) TRIFLUOROMETHANESULFONATE INDIUM(III) TRIFLUOROMETHANESULFONATE (INDIUM TRIFLATE) INDIUM(III)TRIFLUOROMETHANESULPHONATE INDIUM(LLL) TRIFLUOROMETHANESULFONATE In(OTf)3 In(TFA)3 Indium(III) triflate Trifluoromethanesulfonic acid indium(III) salt Tris(trifluoromethanesulfonato)indium Indium triflate Indium trifluoromethanesulphonate 98% Indium(III) triflate Indium(III) trifluoromethanesulfonate, 99% min Indium(III) trifluoromethanesulphonate, 98+% Indium(III)trifluoromethanesulfonate,99%(Indiumtriflate) IndiumtrifluoromethanesulfonateIndiumtriflatepowder Indiumtrifluoromethanesulphonate98% 三氟甲烷磺酸铟 三氟甲磺酸铟 |
| PubChem Substance ID | 24867732 |
| Chemical Name Translation | 三氟甲磺酸铟 |
| MDL Number | MFCD00144478 |
| CAS Number | 128008-30-0 |
| LabNetwork Molecule ID | LN00200521 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Indium
相关文献及参考
- Mild catalyst for the formation of 1,3-dithianes from carbonyl compounds with 1,3-Propanedithiol, A15261: Tetrahedron, 58, 7897 (2002), and of 1,3-oxathiolanes with 2-Mercaptoethanol, A15890: Synlett, 1535 (2002).
- Also catalyzes intramolecular Diels-Alder reactions, with microwave irradiation; the catalyst is potentially reusable: Tetrahedron Lett., 41, 8639 (2000).
- Catalyzes the dehydration of aldoximes to nitriles; ketoximes undergo the Beckmann rearrangement to give amides or lactams: Indian J. Chem., 41B, 154 (2002).
- Superior to Indium(III) chloride, L18758, for the sulfonylation of both activated and deactivated aromatic rings with arylsulfonyl chlorides: Synlett, 830 (2001).
- Catalyst for hetero Diels-Alder reactions, e.g. of 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, L14672 with imines: Tetrahedron Lett., 40, 5621 (1999):
- Catalyst for efficient acylation of alcohols, phenols and amines, which can be acetylated in high yield with 0.1 mol% of catalyst: Synlett, 1743 (1999).
- For a brief feature on uses of this reagent in synthesis, see: Synlett, 899 (2003).
- Effective catalyst for tetrahydropyranylation and depyranylation of alcohols: Tetrahedron Lett., 43, 7975 (2002).
- Superior to several other metal triflates in the Fridel-Crafts reaction of aromatic compounds with Methyl trifluoropyruvate, B21589: Synlett, 555 (2004).
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- Sigma Aldrich:128008-30-0(sigmaaldrich)
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