Pyridinium Fluorochromate 氟铬酸吡啶酯
CAS 83042-08-4 MFCD00151617
化学结构图
SMILES: O[Cr](=O)(=O)F.C1=CC=CC=N1
化学属性
| Mol. Formula | C5H6CrFNO3 |
|---|---|
| Mol. Weight | 199.10 |
| Melting Point | 160-165 |
| TSCA | No |
别名和识别编码
| Chemical Name | Pyridinium Fluorochromate |
|---|---|
| MDL Number | MFCD00151617 |
| PubChem Substance ID | 87575195 |
| CAS Number | 83042-08-4 |
| Reaxys-RN | 4213213 |
| Chemical Name Translation | 氟铬酸吡啶酯 |
| Beilstein Registry Number | 4213213 |
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分类
- {SA} Building Blocks, C5, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
相关文献及参考
- Selective oxidant, less acidic than PCC (Pyridinium chlorochromate, A11752) for high-yield conversion of primary and secondary alcohols to carbonyl compounds: Synthesis, 588 (1982). Enables selective oxidation of a secondary alcohol in the presence of the TBDMS ether of a primary alcohol, where PCC causes cleavage: Bull. Chem. Soc. Jpn., 57, 2019 (1984).
安全信息
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S17 Keep away from combustible material 远离可燃物料；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
- R50/53
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R49 May cause cancer by inhalation 吸入会致癌
- H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P308+P313
- P403+P233
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
- P302+P350
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P304+P340+P311
GHS Symbol
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