Tri(2-furyl)phosphine 三(2-呋喃基)膦

CAS 5518-52-5 MFCD00151857

化学结构图

5518-52-5
SMILES: c1coc(P(c2ccco2)c2ccco2)c1

化学属性

TSCANo
Density1.422
Flash Point136°C/4mm
Mol. FormulaC12H9O3P
Mol. Weight232.17
Appearance white pwdr.
Stabilityair sensitive
Boiling Point286.4°C at 760 mmHg
Melting Point59-64°C

别名和识别编码

Chemical NameTri(2-furyl)phosphine
Synonym Tri-2-furanylphosphine {LY} Tri-2-furanylphosphine {} {LY} Tri-2-furanylphosphine {} {} {LY} Tri-2-furanylphosphine {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {}
EC Number000-000-0
Beilstein Registry Number1577564
PubChem Substance ID521585
Chemical Name Translation三(2-呋喃基)膦
Reaxys-RN1577564
LabNetwork Molecule IDLN00188600
InChIInChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
MDL NumberMFCD00151857
CAS Number5518-52-5
Canonical SMILESP(C1=CC=CO1)(C2=CC=CO2)C3=CC=CO3
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
  • Aromatics
  • Heterocycles
  • Chelating Agents & Ligands,
  • {uni_hamburg} no charge; oxygen heterocycle; aromatic; 5ring; 1fragment

产品应用

  • 磷化氢配体，用于过渡金属介入的有机合成； 也用于Wittig 反应。

相关文献及参考

  • In a study of Pd-catalyzed coupling reactions in supercritical CO 2, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)­phenyl­]phosphine, L06941.
  • Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).
  • Short: III/35C4
  • Beilstein:18(5)12,505
  • Large rate enhancements (10 2 -10 3 ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).
  • Andersen N.G. et al.: Chem. Rev., 101, 997 (2001); Appel M. et al.: Eur. J. Org. Chem., 1143, (2002);

安全信息

Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Signal word Warning
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Store at room temperature {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote

其他信息

  • TCI Shanghai:三(2-呋喃基)膦 Tri(2-furyl)phosphine,>;96.0%(GC)(5518-52-5)
  • F:10-23
  • Sigma Aldrich:5518-52-5(sigmaaldrich)
  • 用途一:磷化氢配体，用于过渡金属介入的有机合成； 也用于Wittig 反应。
  • MOL 文件:5518-52-5.mol
  • Acros Organics:三（2-呋喃基）磷 Tri-(2-furyl)phosphine, 98%(5518-52-5)
  • color:faintly brown
  • 三(2-呋喃)磷化氢价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1643 三(2-呋喃基)膦 Tri(2-furyl)phosphine 5G 2150元 2014/06/02 T1643 三(2-呋喃基)膦 Tri(2-furyl)phosphine 1G 697元 2010/06/21 294802500 三(2-呋喃)磷化氢 Tri-(2-furyl)phosphine 98% 250 MG 492元
  • Alfa Aesar:三(2-呋喃基)膦,97% Tri(2-furyl)phosphine, 97%(5518-52-5)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Others - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Ligands
  2. 96-1650 Phosphine Ligand Kit for Palladium-Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation
  1. Phosphine
  2. 96-1650 Phosphine Ligand Kit for Palladium-Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation

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