Potassium ferrocyanide trihyrate 六氰基亚铁(II)酸钾三水合物

CAS 14459-95-1 MFCD00167023

化学结构图

14459-95-1
SMILES: O.O.O.[K+].[K+].[K+].[K+].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N

化学属性

Mol. FormulaC6H6FeK4N6O3
Mol. Weight422.39
Melting Point70 °C
Density1.85
TSCAYes
Solubility270 G/L (12 ºC)
Stability对光敏感,对湿度敏感

别名和识别编码

Chemical NamePotassium ferrocyanide trihyrate
Synonym Tetrapotassium hexacyanoferrate trihydrate {LY} Tetrapotassium hexacyanoferrate trihydrate {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {} {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrapotassium hexacyanoferrate trihydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrapotassium hexacyano
PubChem Substance ID57651742
EC Number237-722-2
MDL NumberMFCD00167023
CAS Number14459-95-1
Merck Number14,7631
Beilstein Registry Number2384789
Chemical Name Translation六氰基亚铁(II)酸钾三水合物
LabNetwork Molecule IDLN02183983
Canonical SMILESN#[C-][Fe+2]([C-]#N)([C-]#N)([C-]#N)([C-]#N)[C-]#N.[K+].[K+].[K+].[K+].O.O.O
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分类

  • {uni_hamburg} no charge; metal-organic; cyanide; 8fragments; ionic
  • {SNA} ACS Grade, Catalysis and Inorganic Chemistry, Chemical Synthesis, Core Bioreagents, Essential Chemicals, General Reagents, Inorganic Salts, Solutions and Reagents, Iron, Life Science Reagents for Transfection, Research Essentials
  • {SNA} Essential Chemicals, Iron Salts, Metal and Ceramic Science, Research Essentials, Salts, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Core Bioreagents, Essential Chemicals, General Reagents, Iron, Iron Salts, Life Science Reagents for Transfection,

产品应用

  • 高铁试剂(形成普鲁士蓝)。检定铁、铜、锌、钯、银、锇和蛋白试剂、尿液检验。点滴分析钯、锇、铀

相关文献及参考

  • Short: EINECS
  • Short: III/31a
  • Merck: 14,7631 Beilstein: 2,IV,67
  • Merck: 14,7631
  • Replacement for highly toxic metal cyanides in a procedure for cyanation of heteroaryl bromides, utilizing CuI as catalyst in the presence of a suitable ligand, particularly N-alkylimidazoles, e.g. N-(n-Butyl)­imidazole, L07793: Synlett, 555 (2007).

安全信息

WGK Germany2
Hazard statements
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Gloves
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
RTECSLJ9219000
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R52/53
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
Signal word Warning
GHS Symbol
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 溶于水,不溶于醇。稍有风化性。60℃时开始失水,加热至70℃失去结晶水,100℃成无水物。溶于5份水,溶于丙酮,不溶于乙醇和乙醚、醋酸乙酯、液氨。其溶液在光线及空气中易变质,不与热酸和浓酸混合或将溶液置于日光下,以防产生氰化氢。在溶液中含约0.2%碳酸钾,可稳定数月。低毒,半数致死量(大鼠,经口)1600-3200mg/kg。

系列性分类