1-(((1H-Benzo[D][1,2,3]Triazol-1-Yl)Oxy)(Piperidin-1-Yl)Methylene)Piperidin-1-Ium Hexafluorophosphate(V) O-(苯并三氮唑-1-基)-N,N,N’,N’-双(五亚甲基)脲六氟磷酸盐

CAS 206752-41-2 MFCD00191769

化学结构图

206752-41-2
SMILES: F[P-](F)(F)(F)(F)F.C1CCCCN1[C+](ON1N=NC2C=CC=CC1=2)N1CCCCC1

化学属性

Mol. FormulaC17H24F6N5OP
Mol. Weight459.38
Melting Point206° dec.
TSCANo

别名和识别编码

Chemical Name1-(((1H-Benzo[D][1,2,3]Triazol-1-Yl)Oxy)(Piperidin-1-Yl)Methylene)Piperidin-1-Ium Hexafluorophosphate(V)
Synonym O-苯并三唑-1-基-N,N,N',N'-二(五亚甲基)六氟磷酸脲 HBPipU O-苯并三唑-1-基-N,N,N',N'-二(五亚甲基)六氟磷酸脲 HBPipU (1H-Benzotriazol-1-yloxy)dipiperidinocarbenium hexafluorophosphate
MDL NumberMFCD00191769
PubChem Substance ID160871174
CAS Number206752-41-2
Reaxys-RN11179552
Chemical Name TranslationO-(苯并三氮唑-1-基)-N,N,N’,N’-双(五亚甲基)脲六氟磷酸盐
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分类

  • {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents

相关文献及参考

  • 1. Peng Li and Jie Cheng Xu J. Org. Chem. 65 , 2951-2958, (2000)
  • 2. Richard T. Pon, et al Bioconjug. Chem. 10 , 1051-1057, (1999) 摘要
  • 4. S. Chen, J. Xu Tetrahedron Lett. 33 , 647, (1992)
  • 3. P. Henklein et al. Proc. 24th Eur. Pept. Symp.: Peptides 1996 Kingswinford, UK , (1998), 465

安全信息

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Signal word Warning {} {} {TCI}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
WGK Germany3
Storage condition Moisture Sensitive 0-10 0-10°C
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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