3-Methoxybenzyl Bromide 3-甲氧基溴苄

CAS 874-98-6 MFCD00216590

化学结构图

874-98-6
SMILES: COc1cccc(CBr)c1

化学属性

Mol. FormulaC8H9BrO
Mol. Weight201.06
Density1.436 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.575(lit.)
Boiling Point152°C at 760 mmHg
Flash Point113°C

别名和识别编码

Chemical Name3-Methoxybenzyl Bromide
CAS Number874-98-6
Synonym 1-(Bromomethyl)-3-methoxybenzene {LY} 1-(Bromomethyl)-3-methoxybenzene {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00216590
EC Number250-023-7
Beilstein Registry Number2384789
PubChem Substance ID4067207
Alfabeta NameMETHOXYBENZYLBROMIDE 3-
Chemical Name Translation3-甲氧基溴苄
LabNetwork Molecule IDLN00335117
InChIInChI=1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3
Canonical SMILESCOC1=CC(CBr)=CC=C1
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分类

  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • Aromatics
  • Catalyst
  • {SNA} Building Blocks, C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds

产品应用

  • A benzyl bromide derivative used as a benzyl group rearrangement catalyst.

相关文献及参考

  • Nagao, Y. et al.: Chem. Pharm. Bull., 36, 509 (1988);

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Warnings IRRITANT
Hazard Codes C
UN Number UN 3265 8/PG 2
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:874-98-6(sigmaaldrich)
  • 检测方法:HPLC,GC,NMR
  • Acros Organics:3-甲氧基苄溴 3-Methoxybenzylbromide(874-98-6)
  • 3-甲氧基苄溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 393110050 3-甲氧基苄溴 3-Methoxybenzyl bromide 98+% 5 GR 458元 2010/06/21 393110250 3-甲氧基苄溴 3-Methoxybenzyl bromide 98+% 25 GR 1580元
  • 存储注意事项:氮气保护
  • Hazard Note:Corrosive
  • MOL 文件:874-98-6.mol
  • 上游原料:乙酸乙酯 --> 乙醚 --> 石油醚 --> 碳酸氢钠 --> 四氯化碳 --> N-溴代丁二酰亚胺 --> 三溴化磷 --> 甲基叔丁基醚 --> 间甲基苯甲醚 --> 间甲氧基苯甲醇

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C9 - Ethers

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