(R)-2-(2-(Diphenylphosphino)phenyl)-4-Isopropyl-4,5-Dihydrooxazole (R)-(+)-2-[2-(二苯基膦)苯基]-4-(1-甲基乙基)-4,5-二氢噁唑

CAS 164858-78-0 MFCD02684553

化学结构图

164858-78-0
SMILES: CC(C)[C@@H]1COC(=N1)C1C=CC=CC=1P(C1=CC=CC=C1)C1=CC=CC=C1 |&1:3|

化学属性

Mol. FormulaC24H24NOP
Mol. Weight373
Appearance white pwdr.
Stabilityair sensitive
Melting Point77-80°C

别名和识别编码

Chemical Name(R)-2-(2-(Diphenylphosphino)phenyl)-4-Isopropyl-4,5-Dihydrooxazole
Synonym (R)-(+)-2-[2-(二苯基膦)苯基]-4,5-二氢-4-异丙基-噁唑 (R)-(+)-2-[2-(二苯基膦)苯基]-4-异丙基-2-噁唑啉
PubChem Substance ID57652428
Beilstein Registry Number8156604
Chemical Name Translation(R)-(+)-2-[2-(二苯基膦)苯基]-4-(1-甲基乙基)-4,5-二氢噁唑
LabNetwork Molecule IDLN00191548
MDL NumberMFCD02684553
CAS Number164858-78-0
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, PHOX, Privileged Ligands and Complexes

产品应用

  • 与铱催化剂进行不对称烷基化反应；手性配体,用于不对称还原反应

相关文献及参考

  • 1. J.P. Janssen, G. Helmchen Tetrahedron Lett. 38 , 8025 , (1997)
  • 2. A. Lightfoot et al. Angew. Chem. 110 , 3047, (1998)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Safety Statements
Precautionary statements
Storage condition 储存温度2-8℃

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Oxazolines/Oxazolidines 恶唑啉/恶唑烷
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. PHOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. PHOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. DuPhos/BPE
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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