1,2-Cyclohexanedione 1,2-环己二酮

CAS 765-87-7 MFCD00001648

化学结构图

765-87-7
SMILES: O=C1CCCCC1=O

化学属性

Mol. FormulaC6H8O2
Mol. Weight112
Boiling Point193-195
Melting Point34-38
Density1.12
Refractive index1.5190
Flash Point84°(183°F)
TSCAYes
Solubility可溶
Stability充氩操作和储存

别名和识别编码

Chemical Name1,2-Cyclohexanedione
Beilstein Registry Number507419
PubChem Substance ID13006
CAS Number765-87-7
EC Number212-155-3
MDL NumberMFCD00001648
Reaxys-RN507419
Synonym 2-环己烷二酮 1,2-Dioxocyclohexane 氢化邻苯二酚 1,2-环己二酮 Dihydrocatechol Cyclohexane-1,2-dione
Chemical Name Translation1,2-环己二酮
InChIKeyOILAIQUEIWYQPH-UHFFFAOYSA-N
Wiswesser Line NotationL6VVTJ
LabNetwork Molecule IDLN00008434
InChIInChI=1S/C6H8O2/c7-5-3-1-2-4-6(5)8/h1-4H2
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分类

  • {SNA} Bioactive Small Molecules, Building Blocks, C3 to C6, CI-CY, Carbonyl Compounds, Chemical Synthesis, Ketones, Molecular Biology, Organic Building Blocks, Protein Modification, Protein Structural Analysis, Proteomics, Reagents for arginine modification, Specific Amino Acid Modification, 细胞生物学
  • {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks, Protein Modification, Reagents for arginine modification, Specific Amino Acid Modification, 分子生物学,

产品应用

  • 精氨酸残基的特异性试剂

相关文献及参考

  • Protection of trans-1,2-diols as cyclic diacetals has been accomplished by Ley's group using the diketone in combination with trimethyl orthoformate and camphorsulfonic acid. The method is particularly applicable to the carbohydrate field: Synlett, 793 (1996):
  • Beil. 7 ,IV,1982
  • Protection of trans-1,2-diols as cyclic diacetals has been accomplished by Ley's group using the diketone in combination with trimethyl orthoformate and camphorsulfonic acid. The method is particularly applicable to the carbohydrate field: Synlett, 793 (1996):
  • Undergoes copper-catalyzed oxidative cleavage to give 2-halo diacids: Synthesis, 917 (1992):
  • See also Org. Synth., 75, 170 (1997), for an alternative method.
  • Undergoes copper-catalyzed oxidative cleavage to give 2-halo diacids: Synthesis, 917 (1992):
  • 2. Biochemistry 18 , 4605, (1979) 摘要
  • See also Org. Synth., 75, 170 (1997), for an alternative method.

安全信息

WGK Germany3
RTECSGV0340000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xn
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
Storage condition 储存温度-20°C 储存温度2-8°C
GHS Symbol
Safety Statements
Precautionary statements
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 67,367,1979

系列性分类


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