(S,S',R,R')-TangPhos

CAS 470480-32-1 MFCD06658118

化学结构图

470480-32-1
SMILES: CC(C)(C)P1CCC[C@@H]1[C@H]1CCCP1C(C)(C)C

化学属性

Mol. FormulaC16H32P2
Mol. Weight286.37
Melting Point60-65 °C

别名和识别编码

Chemical Name(S,S',R,R')-TangPhos
Synonym (S,S′,R,R′)-TangPhos (1S,1S′,2R,2R′)-1,1′-二叔丁基-(2,2′)-二磷烷
PubChem Substance ID24883788
CAS Number470480-32-1
Chemical Name Translation
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes

相关文献及参考

  • 1. Noh, D.; et al., An Efficient copper(I)-catalyst system for the asymmetric hydroboration of ß-substituted vinylarenes with pinacolborane Chem. Asian J. 6 , 1967-1969, (2011)
  • 2. He, S.; et al., Catalytic asymmetric hydrogenation to access spiroindane dimethyl acetic acid Tetrahedron Lett. 52 , 3621-3624, (2011)
  • 3. Lu, N.; et al., Theoretical mechanistic study of TangPhos-catalyzed asymmetric γ addition of thiols to allenoates J. Mol. Catal. A: Chem. 339 , 99-107, (2011)
  • 4. Gonzalez-Rodriguez, C.; et al., Rhodium-catalyzed intermolecular alkyne hydroacylation: the enantio- selective synthesis of α- and β-substituted ketones by kinetic resolution Chem. Eur. J. 16 , 10950-10954, (2010)
  • 5. Ma, M.; et al., Highly efficient RhI-catalyzed asymmetric hydrogenation of β-amino acrylonitriles Chem. Eur. J. 16 , 5301-5304, (2010)
  • 6. Tang, W.; Zhang, X. Angew. Chem. Int. Ed. Engl. 41 , 1612, (2002)
  • 7. Tang, W.; Zhang, X. Org. Lett. 4 , 4159, (2002) 摘要
  • 8. Tang, W. et al. Org. Lett. 5 , 205, (2003) 摘要
  • 9. Axtell, A. T. et al. Organometallics 25 , 5003, (2006)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类


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