(S)-SIPHOS-PE (11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1', 7'-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺
CAS 500997-70-6 MFCD08459342
化学结构图
SMILES: C[C@@H](C1C=CC=CC=1)N(C(C)C1C=CC=CC=1)P1OC2=CC=CC3CCC4(CCC5C=CC=C(O1)C4=5)C=32 |&1:1|
化学属性
| Density | 1.422 |
|---|---|
| Mol. Formula | C33H32NO2P |
| Mol. Weight | 505.59 |
| Appearance | white solid |
| Stability | moisture sensitive |
| Melting Point | 99-101°C |
别名和识别编码
| Chemical Name | (S)-SIPHOS-PE |
|---|---|
| Synonym | (11aR)-(+)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺 N-二[(R)-1-苯乙基]-[(R)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺 (11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺 (11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺 N-二[(R)-1-苯乙基]-[(S)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺 (S)-SIPHOS-PE N-二[(R)-1-苯乙基]-[(S)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | (11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1', 7'-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺 |
| PubChem Substance ID | 329762229 |
| MDL Number | MFCD08459342 |
| CAS Number | 500997-70-6 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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