Lithium diisobutyl-tert-butoxyaluminum hydride 二异丁基-叔丁氧基氢化铝锂

CAS 77299-63-9 MFCD16621454

化学结构图

77299-63-9
SMILES:

化学属性

Density0.795 g/mL at 25 °C
Mol. Weight222.27
Mol. FormulaC12H28AlLiO

别名和识别编码

Synonym 二异丁基-叔丁氧基氢化铝锂 溶液 LDBBA
MDL NumberMFCD16621454
Chemical NameLithium diisobutyl-tert-butoxyaluminum hydride
Chemical Name Translation二异丁基-叔丁氧基氢化铝锂
PubChem Substance ID329763573
CAS Number77299-63-9
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分类

  • {SNA} Aluminum Hydrides, Chemical Synthesis, Organoaluminum, Organometallic Reagents, Reduction, Synthetic Reagents

安全信息

Hazard Codes F,Xn,N
WGK Germany3
GHS Symbol
Precautionary statements
  • P402+P404
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+P378
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Signal word Danger
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
Risk Statements
  • R48/20
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R51/53
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Aluminum Hydrides - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Metal Hydrides 金属氢化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Metal Hydrides 金属氢化物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum

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