Isobutyl acrylate 丙烯酸异丁酯

CAS 106-63-8 MFCD00042865

化学结构图

106-63-8
SMILES: C=CC(=O)OCC(C)C

化学属性

Mol. FormulaC7H12O2
Mol. Weight128
Refractive index1.4120 to 1.4160
Boiling Point132
Density0.89
Flash Point31°C(lit.)
TSCAYes
Melting Point-61
Solubility微溶于水。

别名和识别编码

Chemical NameIsobutyl acrylate
CAS Number106-63-8
PubChem Substance ID7819
EC Number203-417-8
Beilstein Registry Number1749388
MDL NumberMFCD00042865
Reaxys-RN1749388
Synonym 2-methylpropylacrylate 2-propenoicacid,isobutylester 2-丙烯酸-2-甲基丙酯 Acrylic acid isobutyl ester Acrylsäure-isobutylester ISOBUTYL ACRYLATE ISOBUTYL ACRYLATE, 99+% Isobutyl propenoate Isobutylacrylat Isobutylester kyseliny akrylove Z-Methylpropyl acrylate propenoicacid,isobutylester 丙烯酸異丁酯
Chemical Name Translation丙烯酸异丁酯
Wiswesser Line Notation1Y1&1OV1U1
LabNetwork Molecule IDLN00224366
InChIInChI=1S/C7H12O2/c1-4-7(8)9-5-6(2)3/h4,6H,1,5H2,2-3H3
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • {SNA} Acrylate,
  • Acrylate, Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis,
  • {SNA} Acrylate, Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Monomers, Organic Building Blocks, Polymer Science, 材料科学
  • {SNA} Acrylate, Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Materials Science, Monomers,

相关文献及参考

  • Beilstein:2(4)1465
  • Short: EINECS
  • Short: III/38B
  • Short: IV/20B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H312 Harmful in contact with skin 皮肤接触有害
  • H312+H332
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 Xn
RTECSAT2100000
Precautionary statements
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P304+P340+P312
  • P337+P313
  • P370+P378
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number 2527
Risk Statements
  • R10 Flammable 易燃
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Safety Statements
  • S2 Keep out of the reach of children 避免儿童触及;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S37 Wear suitable gloves 戴适当手套;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Packing GroupIII
Hazard Class3
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 891 uL/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Gastrointestinal - ulceration or bleeding from stomach
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0535072

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 654 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 36,58,1975

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2000 ppm/4H
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0535072

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 760 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JDREAF Journal of Dental Research.  (International Assoc. for Dental
   Research, 734 15th St., NW, Suite 809, Washin

其他信息

  • TCI Shanghai:丙烯酸异丁基酯(含稳定剂甲氧基氢醌) Isobutyl Acrylate (stabilized with MEHQ),>;99.0%(GC)(106-63-8)
  • MOL 文件:106-63-8.mol
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运
  • 刺激数据:皮肤-兔子 500 毫克 轻度; 眼睛-兔子 500 毫克/24小时 轻度
  • 可燃性危险特性:易燃; 聚合大量放热
  • 灭火剂:干粉, 二氧化碳, 砂土, 泡沫
  • 毒性分级:低毒
  • Alfa Aesar:丙烯酸异丁酯,99%,stab.with100ppm4-methoxyphenol Isobutyl acrylate, 99%, stab with 100ppm 4-methoxyphenol(106-63-8)
  • 图谱信息:丙烯酸异丁酯(106-63-8)核磁图( 13 CNMR) 丙烯酸异丁酯(106-63-8)质谱(MS) 丙烯酸异丁酯(106-63-8)Raman光谱 丙烯酸异丁酯(106-63-8)核磁图( 1 HNMR) 丙烯酸异丁酯(106-63-8)红外图谱(IR1) 丙烯酸异丁酯(106-63-8)红外图谱(IR2)
  • 类别:易燃液体
  • 下游产品:LT-01 乳胶
  • 外观性质:无色液体。
  • Sigma Aldrich:106-63-8(sigmaaldrich)
  • 丙烯酸异丁酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0747 丙烯酸异丁酯(含稳定剂MEHQ) Isobutyl Acrylate (stabilized with MEHQ) 500ML 397元 2014/06/02 A0747 丙烯酸异丁酯(含稳定剂MEHQ) Isobutyl Acrylate (stabilized with MEHQ) 25ML 241元 2010/05/25 L12739 丙烯酸异丁酯, 99%, stab. with 100ppm 4-methoxyphenol Isobutyl acrylate, 99%, stab with 100ppm 4-methoxyphenol 500ml 741元
  • MSDS 信息:丙烯酸异丁酯(106-63-8).msds
  • 急性毒性:口服-大鼠 LD50: 5967 毫克/公斤; 口服-小鼠 LD50: 6106 毫克/公斤
  • 爆炸物危险特性:蒸气与空气混合可爆

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