(Ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) 二甲基丙烯酸三乙二醇酯

CAS 109-16-0 MFCD00008591

化学结构图

109-16-0
SMILES: C=C(C)C(=O)OCCOCCOCCOC(=O)C(=C)C

化学属性

Mol. FormulaC14H22O6
Mol. Weight286
Refractive index1.4600 to 1.4620
Density1.092
Boiling Point155°C/1mmHg(lit.)
Flash Point159°C(lit.)
Stability对光线敏感
Melting Point-52°C

别名和识别编码

Chemical Name(Ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)
CAS Number109-16-0
Synonym polyestertgm3 聚酯树脂 黑色PET Triethylene glycol dimethacrylate methacrylicacid,diesterwithtriethyleneglycol Ethylenebis(oxyethylene) methacrylate 甲基丙烯酸二缩乙二醇酯 nkester3g ######## 1,2-bis(2-(methacryloyloxy)ethoxy)ethane Polyester TGM-3 三甘醇二-2-甲基丙烯酸酯 二甲基丙烯酸三乙二醇酯 2,2'-Ethylenedioxydiethyl dimethacrylate; Ethane-1,2-diylbis(oxyethane-2,1-diyl) bis(2-methylacrylate) Tedma 双甲基丙烯酸二缩三乙二醇酯 polyestertgm-3 NK ester 3G Polyester TGM 3 1,2-Bis[2-(Methacryloyloxy)ethoxy]ethane ethylenebis(oxyethylene)methacrylate 二缩三乙二醇双甲基丙烯酸酯 二甲基丙烯酸三甘醇酯 2-Propenoic acid, 2-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester TRIETHYLENE GLYCOL DIMETHACRYLATE TEDMA TGM 35 2-Propenoicacid,2-methyl-,1,2-ethanediylbis(oxy-2,1-ethanediyl)ester 三甘醇二甲基丙烯酸酯 涤纶色母粒 黑色涤纶母粒 METHACRYLIC ACID TRIETHYLENEGLYCOL DIESTER 三乙二醇二甲基丙烯酸酯 TGM 3S NK Ester 3G TGM 3 2-(2-[2-(Methacryloyloxy)ethoxy]ethoxy)ethyl 2-methylacrylate 聚三乙二醇二甲基丙烯酸酯 TGM 3PC Methacrylic acid, diester with triethylene glycol
MDL NumberMFCD00008591
EC Number203-652-6
Beilstein Registry Number1797351
PubChem Substance ID7979
Reaxys-RN1797351
Chemical Name Translation二甲基丙烯酸三乙二醇酯
LabNetwork Molecule IDLN00193598
InChIInChI=1S/C14H22O6/c1-11(2)13(15)19-9-7-17-5-6-18-8-10-20-14(16)12(3)4/h1,3,5-10H2,2,4H3
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分类

  • {SNA} Biomaterials, Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Crosslinking Agents, Esters, Homobifunctional PEGs, Materials Science, Methacrylate, Organic Building Blocks,
  • Mutagenesis Research Chemicals
  • {SNA} Biomaterials, Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis,
  • {SNA} Crosslinkers, Crosslinking Agents, Homobifunctional PEGs, Methacrylate, Poly(ethylene glycol) and Poly(ethylene oxide), Polymer Science, Polymers, Reagents for Polymerization, 材料科学
  • {SNA} Biomaterials, Building
  • {SN

产品应用

  • Esters of acrylic acid and methacrylic acid, more commonly known as acrylates and methacrylates are key raw materials in the coatings and printing industry, and in food packaging.

相关文献及参考

  • Beilstein: 2,IV,1531
  • McCarthy, K., et al.: Food Chem. Toxicol., 30, 505 (1992),
  • Moore, M., et al.: Mutagenesis, 6, 77 (1991),

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Precautionary statements
  • P333+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P304+P340+P312
  • P302+P352+P333+P313+P362+P364
  • P403+P233
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
Signal word
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSOZ4100000
Hazard Codes Xi
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C 储存温度2-8°C 2-8℃ 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10837 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 47(4),17,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10750 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 47(4),17,1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 4 mg/plate
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year:
   31(Suppl),214,1986

其他信息

  • 三乙二醇二甲基丙烯酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A26154801 三乙二醇二甲基丙烯酸酯 250ml 643元 2011/04/16 T0948 三乙二醇二甲基丙烯酸酯(含稳定剂MEHQ) Triethylene Glycol Dimethacrylate (stabilized with MEHQ) 500ML 686元 2011/04/16 T0948 三乙二醇二甲基丙烯酸酯(含稳定剂MEHQ) Triethylene Glycol Dimethacrylate (stabilized with MEHQ) 25ML 195元
  • Sigma Aldrich:109-16-0(sigmaaldrich)
  • 下游产品:硫磺 --> 偏苯三酸酐 --> 醇酸底漆 --> 聚乙烯导电塑料 --> 树脂,玻璃布 --> 汽车涂料 --> 热固性粉末涂料 --> 环氧-聚酯混合型粉末涂料 --> 环氧型粉末涂料 --> 聚酯清漆 --> 绝缘磁漆 --> 聚酯水晶地板漆
  • MOL 文件:109-16-0.mol
  • 检测方法:GC
  • 用途一:用于纺制涤纶纤维
  • F:8-19
  • TCI Shanghai:三乙二醇二甲基丙烯酸酯(含稳定剂甲氧基氢醌) Triethylene Glycol Dimethacrylate (stabilized with MEHQ),>;95.0%(GC)(109-16-0)
  • 图谱信息:三乙二醇二甲基丙烯酸酯(109-16-0)核磁图( 13 CNMR) 三乙二醇二甲基丙烯酸酯(109-16-0)核磁图( 1 HNMR) 三乙二醇二甲基丙烯酸酯(109-16-0)红外图谱(IR1) 三乙二醇二甲基丙烯酸酯(109-16-0)质谱(MS)
  • MSDS 信息:Ethane-1,2-diylbis(oxyethane-2,1-diyl) bis(2-methylacrylate)(109-16-0).msds
  • 用途二:广泛用于环氧/聚酯混合型涂料中，使其装饰性、施工性、贮存稳定性方面具有优良性能
  • 上游原料:乙二醇 --> 己二酸 --> 1,4-丁二醇 --> 对苯二甲酸 --> 偏苯三酸酐 --> 2,2-二甲基-1,3-丙二醇
  • 存储注意事项:光敏感
  • 用途三:是涤纶长丝、涤纶短纤维纺前着色用理想着色剂

系列性分类

  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Poly(ethylene glycol) and Poly(ethylene oxide) 聚乙二醇和聚环氧乙烷
  4. Homobifunctional PEGs - Poly(ethylene glycol) and Poly(ethylene oxide)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C12 to C63 - Esters
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymer Additives - Polymer Science
  4. Crosslinkers - Polymer Additives

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