Acet-o-Toluidide 2-甲基乙酰苯胺

CAS 120-66-1 MFCD00014961

化学结构图

120-66-1
SMILES: CC(=O)Nc1ccccc1C

化学属性

Mol. FormulaC9H11NO
Mol. Weight149
Density1.16
TSCAYes
Boiling Point296
Melting Point108.0 to 112.0 deg-C
Flash Point296°C

别名和识别编码

Chemical NameAcet-o-Toluidide
Synonym {uni_hamburg} n-(2-methylphenyl)-acetamid 2-methyl-acetanilide O-ACETOTOLUIDIDE 2-ACETOTOLUIDINE o-Acetyltoluidide N-(o-Methylphenyl)acetamide N-乙醯鄰【草(之上)+叨】胺 N-ACETYL-O-TOLUIDINE N-o-Tolyl-acetamide O-ACETOTOLUIDINE o-Acetamidotoluene 2-Methylacetanilide o-Acetotoluidide 2'-METHYLACETANILIDE Essigsäure-o-toluidid N-(2-Methyl-phenyl)acetamide Acetyl-o-toluidine o-Acetotoluidide o-Acetotoluide Acetamide, N-(2-methylphenyl)- 2-ACETAMIDOTOLUENE N-o-Tolyl-acetamide ACETYL-O-TOLUIDINE O-METHYLACETANILIDE N-2-Methyl-phenylacetamide N
MDL NumberMFCD00014961
CAS Number120-66-1
EC Number204-414-4
Beilstein Registry Number2207054
Merck Number74
Reaxys-RN2207054
PubChem Substance ID87561763
Chemical Name Translation2-甲基乙酰苯胺
Wiswesser Line Notation1VMR B1
LabNetwork Molecule IDLN00239839
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; amide; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSAN2900000
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1450 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   19,20,1971

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,9,1953

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   NTPTB* NTP Technical Bulletin.  (National Toxicology Program, Landow Bldg.
   3A-06, 7910 Woodmont Ave., Bethesda, MD 20205)  Volume(issue)/page/year:
   JAN1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 47 nmol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 137,39,1984

其他信息

  • 下游产品:2-氨基-4-硝基甲苯 --> 2-甲基-6-硝基苯胺
  • 2-甲基乙酰苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A0063 乙酰邻甲苯胺 o-Acetotoluidine 500G 1650元 2011/04/16 A0063 乙酰邻甲苯胺 o-Acetotoluidine 25G 248元 2010/05/25 A13235 2'-甲基乙酰苯胺, 98+% 2'-Methylacetanilide, 98+% 25g 279元
  • 图谱信息:2-甲基乙酰苯胺(120-66-1)核磁图( 1 HNMR) 2-甲基乙酰苯胺(120-66-1)核磁图( 13 CNMR) 2-甲基乙酰苯胺(120-66-1)红外图谱(IR1) 2-甲基乙酰苯胺(120-66-1)质谱(MS) 2-甲基乙酰苯胺(120-66-1)红外图谱(IR2)
  • 储运特性:库房通风低温干燥
  • 毒性分级:中毒
  • TCI Shanghai:乙酰邻甲苯胺 o-Acetotoluidine,>;98.0%(T)(120-66-1)
  • Sigma Aldrich:120-66-1(sigmaaldrich)
  • Alfa Aesar:2'-甲基乙酰苯胺,98+% 2'-Methylacetanilide, 98+%(120-66-1)
  • 急性毒性:口服- 小鼠 LD50: 1450 毫克/ 公斤
  • MOL 文件:120-66-1.mol
  • 可燃性危险特性:可燃; 加热分解释放有毒氮氧化物烟雾
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 上游原料:乙酸 --> 乙酐 --> 邻甲基苯胺
  • 检测方法:HPLC,NMR
  • 2-甲基乙酰苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0063 乙酰邻甲苯胺 o-Acetotoluidine 500G 1650元 2014/06/02 A0063 乙酰邻甲苯胺 o-Acetotoluidine 25G 248元 2010/05/25 A13235 2'-甲基乙酰苯胺, 98+% 2'-Methylacetanilide, 98+% 25g 279元
  • Hazard Note:Harmful
  • 类别:有毒物品

系列性分类


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