Bis(cyclopentadienyl)chromium(II) 双(环戊二烯)铬

CAS 1271-24-5 MFCD00013750

化学结构图

1271-24-5
SMILES: [CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Cr]

化学属性

TSCAYes
Mol. FormulaCr(C5H5)2
Mol. Weight182
Appearance scarlet xtl.
Stabilityair sensitive
Melting Point172-173°C

别名和识别编码

Chemical NameBis(cyclopentadienyl)chromium(II)
Synonym Bis(η5-cyclopentadienyl)chromium(II) Bis(cyclopentadiene)chromium(II) chromocene bis(cyclopentadienyl)chromium(II) 二茂铬 Chromium, di-pi-cyclopentadienyl- Chromium, dicyclopentadienyl- 双(环戊二烯)铬(II) Chromium, di-π-cyclopentadienyl- 二(环戊二烯基)铬(II) 二茂铬 Bis(eta(5)-cyclopentadienyl)chromium Chromocene, Di(cyclopentadienyl)chromium(II) bis(η5-cyclopenta-2,4-dien-1-yl)chromium 二(环戊二烯基)铬(II) Bis(cyclopentadiene)chromium Bis(cyclopentadienyl)chromium Di(η5-cyclopentadienyl)chromium Dicyclopentadienylchromium Di((eta-5)-cyclopentadienyl)chromium Bis(cyclopentadienyl)chromium(II)
PubChem Substance ID24863782
EC Number215-036-4
Chemical Name Translation双(环戊二烯)铬
MDL NumberMFCD00013750
CAS Number1271-24-5
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分类

  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chromium, Chromium Catalysts, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chromium, Materials Sci

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source
  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes 4.2 Xn
RTECSGB7600000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S8 Keep container dry 保持容器干燥；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S37 Wear suitable gloves 戴适当手套；
UN Number 3391
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition Air & Moisture Sensitive
Packing GroupI 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19(Suppl 21),2,1992

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系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Chromium Catalysis 铬催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Chromium Catalysis 铬催化剂
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Chromium - CVD and ALD Precursors by Metal
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Reagents for Polymerization - Polymer Science
  4. Catalysts for Polymerization - 烯烃聚合催化
  5. Olefin Polymerization - Catalysts for Polymerization
  1. Organometallics for CVD & ALD
  2. Chromium
  1. Metallocenes, Derivatives & Cp Precursors
  2. Chromium