1,2-Diaminoanthraquinone 1,2-二氨基蒽-9,10-二酮

CAS 1758-68-5 MFCD00001219

化学结构图

1758-68-5
SMILES: Nc1ccc2c(c1N)C(=O)c1ccccc1C2=O

化学属性

Mol. FormulaC14
Mol. Weight238
Melting Point289-291 °C (lit.)
TSCAYes
SolubilitySoluble in DMSO (5 mg/ml). Insoluble in water.

别名和识别编码

Chemical Name1,2-Diamino-10-Anthracenedione
MDL NumberMFCD00001219
PubChem Substance ID15652
CAS Number1758-68-5
EC Number217-156-2
Synonym 1,2-DAA 1,2-DIAMINOANTHRAQUINONE 1,2-Daa 1,2-Diamino-9,10-anthracenedione 1,2-Diaminoanthraquinone 1,2-daa 1,2-diamino-10-anthracenedione 1,2-diamino-9,10-anthracenedione 1,2-diamino-9,10-anthraquinone 1,2-diamino-anthraquinon 1,2-diaminoanthracene-9,10-dione 1,2-diaminoanthraquinone 1,2-二氨基-9,10-蒽二酮 1,2-二氨基萘醌 1,2-二氨基蒽醌 1,2-二氨基蒽醌, tech. 90% 10-Anthracenedione,1,2-diamino-9 9,10-Anthracenedione, 1,2-diamino- DAA Diaminoanthraquinone NSC-39934
Beilstein Registry Number2125604
Chemical Name Translation1,2-二氨基蒽-9,10-二酮
Wiswesser Line NotationL C666 BV IVJ DZ EZ
LabNetwork Molecule IDLN00433238
InChIInChI=1S/C14H10N2O2/c15-10-6-5-9-11(12(10)16)14(18)8-4-2-1-3-7(8)13(9)17/h1-6H,15-16H2
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分类

  • Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

产品应用

  • For the direct detection of nitric oxide.

相关文献及参考

  • Beil. 14 ,I,459
  • Aldrich MSDS 1 , 559:D / Corp MSDS 1 (1), 1045:C / FT-IR 2 (2), 2499:B / FT-IR 1 (2), 90:B / IR-Spectra (2), 789:A / IR-Spectra (3), 901:G / NMR-Reference 2 (2), 92:B / RegBook 1 (2), 1691:K / Sax 6 , 881 / Structure Index 1 , 268:C:7

安全信息

RTECSCB6200000
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Storage condition 储存温度2-8℃,充氩保存 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01102

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 21(12),27,1977

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,203,1976

其他信息

  • Sigma Aldrich:1758-68-5(sigmaaldrich)
  • Alfa Aesar:1,2-二氨基蒽醌,95% 1,2-Diaminoanthraquinone, 95%(1758-68-5)
  • MOL 文件:1758-68-5.mol
  • 1,2-Diaminoanthraquinone is a useful reagent for the direct detection of nitric oxide (NO) DAA is non-fluorescent; however, it reacts with NO, in the presence of oxygen, to form DAA triazole, yielding red fluorescence, which is visible with a rhodamine filter (λ ≥ 580 nm).
  • 1,2-二氨基蒽醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L11741 1,2-二氨基蒽醌, 95% 1,2-Diaminoanthraquinone, tech. 90% 5g 178元 2010/05/25 L11741 1,2-二氨基蒽醌, 95% 1,2-Diaminoanthraquinone, tech. 90% 25g 781元
  • 图谱信息:1,2-二氨基蒽醌(1758-68-5)红外图谱(IR1) 1,2-二氨基蒽醌(1758-68-5)质谱(MS)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones

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