2,4-Dihydroxy-6-Methylbenzoic Acid Ethyl Ester 2,4-二羟基-6-甲基苯甲酸乙酯

CAS 2524-37-0 MFCD00010821

化学结构图

2524-37-0
SMILES: CCOC(=O)c1c(C)cc(O)cc1O

化学属性

Mol. FormulaCH3C6H2(OH)2CO2C2H5
Mol. Weight196
Melting Point131.0 to 134.0 deg-C

别名和识别编码

Chemical Name2,4-Dihydroxy-6-Methylbenzoic Acid Ethyl Ester
MDL NumberMFCD00010821
CAS Number2524-37-0
PubChem Substance ID87566330
Alfabeta NameETHYLDIHYDROXYMETHYLBENZOATE 246---,
Synonym 4-CARBETHOXY-5-METHYLRESORCINOL 2,4-dihydroxy-6-methyl-benzoicaciethylester ETHYL 2,4-DIHYDROXY-6-METHYLBENZOATE, 98 % 4-ETHOXYCARBONYL-5-METHYLRESORCINOL 2,4-二羟基-6-甲基苯甲酸乙酯 2-ETHOXYCARBONYL-3,5-DIHYDROXYTOLUENE 2,4-DIHYDROXY-6-METHYLBENZOIC ACID ETHYL ESTER 98+% ETHYL 2,4-DIHYDROXY-6-METHYLBENZOATE 2,4-二羟基-6-甲基甲酸乙酯 Ethyl orsellinate 2-CARBETHOXY-3,5-DIHYDROXYTOLUENE 2,4-DIHYDROXY-6-METHYLBENZOIC ACID ETHYL ESTER
Reaxys-RN2693137
Beilstein Registry Number10(4)1526
Chemical Name Translation2,4-二羟基-6-甲基苯甲酸乙酯
LabNetwork Molecule IDLN00183830
InChIInChI=1S/C10H12O4/c1-3-14-10(13)9-6(2)4-7(11)5-8(9)12/h4-5,11-12H,3H2,1-2H3
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分类

  • {SNA} Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352+P332+P313+P362+P364
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Warnings IRRITANT
Hazard Codes Xi
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

其他信息

  • 方法一:将2,4-二羟基-3,5-二溴-6-甲基苯甲酸乙酯加入氢氧化钠溶液中，在钯/聚乙烯醇催化剂存在下进行氢解。反应后加氯化钠沉淀出催化剂，过滤，滤液酸化后用三氯甲烷萃取，萃取液回收溶液后得2,4-二羟基-6-甲基苯甲酸乙酯。
  • MOL 文件:2524-37-0.mol
  • 用途一:用机合成中间体。
  • Sigma Aldrich:2524-37-0(sigmaaldrich)
  • 上游原料:三氯甲烷 --> 聚乙烯醇 --> 2,4-二羟基-6-甲基苯甲酸 --> 2,4-二羟基-3,5-二溴-6-甲基苯甲酸乙酯
  • TCI Shanghai:2,4-二羟基-6-甲基苯甲酸乙酯 Ethyl 2,4-Dihydroxy-6-methylbenzoate,>;98.0%(T)(2524-37-0)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C10 to C11 - Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C10 to C11 - Esters

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