CAS 2873-97-4 MFCD00008788-Diacetone acrylamide 双丙酮丙烯酰胺 -LabNovo

Diacetone acrylamide 双丙酮丙烯酰胺

CAS 2873-97-4 MFCD00008788

化学结构图

SMILES: C=CC(=O)NC(C)(C)CC(C)=O

化学属性

Mol. Formula	C9H15NO2
Mol. Weight	169.22
Melting Point	53-57°C
Flash Point	139.4°C
TSCA	Yes
Boiling Point	325.9°C at 760 mmHg
Solubility	可溶
Appearance	白色或稍带黄色的片状结晶。熔融时无色。熔点57-58℃，沸点120℃（1.07kPa），93-100℃（13.3-40Pa），相对密度0.998（60/4℃）。溶于水、甲醇、乙醇、丙酮、四氢呋喃、乙酸乙酯、氯甲烷、苯、乙腈、苯乙烯、正己醇等，不溶于石油醚（30-60℃）。
Density	0.965
Stability	易吸潮,对光线敏感

别名和识别编码

Chemical Name	Diacetone acrylamide
Synonym	N-(2-Methyl-4-oxopentan-2-yl)acrylamide {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} {
CAS Number	2873-97-4
PubChem Substance ID	87566810
EC Number	220-713-2
Beilstein Registry Number	1928444
MDL Number	MFCD00008788
Reaxys-RN	1928444
Merck Number	2963
Chemical Name Translation	双丙酮丙烯酰胺
Wiswesser Line Notation	1V1X1&1&MV1U1
LabNetwork Molecule ID	LN00225852
Canonical SMILES	C=CC(NC(C)(CC(C)=O)C)=O

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品牌质保精细包装现货库存一流品牌服务

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H302 Harmful if swallowed 吞食有害

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xn

RTECSAS3475000

Signal word

Precautionary statements

P301+P312+P330
P501 Dispose of contents/container to..… 处理内容物/容器.....
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。

Safety Statements

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R22 Harmful if swallowed 吞咽有害

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1770 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,113,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,113,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1303 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   47,179,1981

其他信息

溶于水，也溶于甲醇、氯仿等大部分有机溶剂；极易与多种单体共聚，形成均聚物，聚合物具有强吸水性。
双丙酮丙烯酰胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 D0062 双丙酮丙烯酰胺(含稳定剂MEHQ + TBC) Diacetone Acrylamide (stabilized with MEHQ) 500G 1090元 2011/04/16 D0062 双丙酮丙烯酰胺(含稳定剂MEHQ + TBC) Diacetone Acrylamide (stabilized with MEHQ) 25G 184元 2010/06/21 352320050 双丙酮丙烯酰胺 Diacetone acrylamide 99% 5 GR 256元
MOL 文件:2873-97-4.mol
用途一:主要作为均聚物使用，广泛用于涂料、耐湿性好的烫发用树脂及喷雾定型剂、感光树脂及其添加剂等
上游原料:四氯化碳
F:3
Acros Organics:双丙酮丙烯酰胺 Diacetone acrylamide, 99%(2873-97-4)
MSDS 信息:N-(1,1-Dimethyl-3-oxobutyl)acrylamide(2873-97-4).msds
双丙酮丙烯酰胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D0062 双丙酮丙烯酰胺(含稳定剂MEHQ + TBC) Diacetone Acrylamide (stabilized with MEHQ) 500G 702元 2014/06/02 D0062 双丙酮丙烯酰胺(含稳定剂MEHQ + TBC) Diacetone Acrylamide (stabilized with MEHQ) 25G 123元 2010/06/21 352320050 双丙酮丙烯酰胺 Diacetone acrylamide 99% 5 GR 256元
敏感性:Hygroscopic
Sigma Aldrich:2873-97-4(sigmaaldrich)
TCI Shanghai:N-(1,1-二甲基-3-氧代丁基)烯丙酰胺(含稳定剂甲氧基氢醌和叔丁基邻苯二酚) Diacetone Acrylamide (stabilized with MEHQ + TBC),>;98.0%(T)(2873-97-4)
方法一:由丙烯腈和丙酮在浓硫酸中反应而得。
Alfa Aesar:二丙酮丙烯酰基酰胺,99% Diacetone acrylamide, 99%(2873-97-4)
用途二:重要的乙烯基单体。聚合生成的均聚物不溶于水，但有“水呼吸性”。吸水率可达树脂自重的20-25%，而当环境湿度低于60%时，聚合物所吸收的水分又释放出来，水分对聚合物来说，起着一种增塑剂的作用。利用这种奇特的性质，可发展多种用途。（1）耐湿润性好的烫发用树脂日本将其用于耐湿气的烫发用树脂，发型保持时间长，雨淋、冲洗不变形。（2）感光树脂将该品用作感光树脂原料的一部分，可有以下特点：感光速度快；曝光后非影像部分容易除去可以得到清晰的影像；能获得强度好、耐溶剂、耐水性好的版面。此外，还可用作不饱和聚酯树脂的交联剂，邻苯二甲酸二烯丙酯的交联剂，环氧树脂的固化剂，如用于“水呼吸性”树脂（接触眼镜、防止玻璃起雾、船底涂料等）、压敏胶粘剂、胶粘改良剂、无纺织物粘合剂、吸水性薄膜、皮革涂饰剂和改良剂、纸力增强剂、防静电聚合物、油墨等。
图谱信息:双丙酮丙烯酰胺(2873-97-4)红外图谱(IR1) 双丙酮丙烯酰胺(2873-97-4)核磁图( 1 HNMR) 双丙酮丙烯酰胺(2873-97-4)核磁图( 13 CNMR) 双丙酮丙烯酰胺(2873-97-4)质谱(MS) 双丙酮丙烯酰胺(2873-97-4)红外图谱(IR2)