2-Iodosobenzoic Acid 2-亚碘酰苯甲酸

CAS 304-91-6 MFCD00002401

化学结构图

304-91-6
SMILES: O=[IH2]c1ccccc1C(=O)O

化学属性

Mol. FormulaC7H5IO3
Mol. Weight264.02
Melting Point230 °C
TSCANo

别名和识别编码

Chemical Name2-Iodosobenzoic Acid
MDL NumberMFCD00002401
CAS Number304-91-6
Synonym 2-Iodosobenzoic {LY} 2-Iodosobenzoic {} {LY} 2-Iodosobenzoic {} {} {LY} 2-Iodosobenzoic {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodosobenzoic
EC Number206-159-4
Beilstein Registry Number1939973
PubChem Substance ID67537
Reaxys-RN1939973
Chemical Name Translation2-亚碘酰苯甲酸
InChIKeyIFPHDUVGLXEIOQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN01742745
InChIInChI=1S/C7H5IO3/c9-7(10)5-3-1-2-4-6(5)8-11/h1-4H,(H,9,10)
Canonical SMILESO=C(O)C1=CC=CC=C1I=O
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分类

  • {SNA} Enzymatic and Chemical Protein Cleavage, Mass Spectrometry, Reagents for Chemical Cleavage of Proteins, 分子生物学, 蛋白质组学
  • {SNA} 分子生物学, 用于蛋白质化学剪切的试剂, 蛋白质组学, 质谱, 酶促及化学蛋白质剪切
  • {SNA} Enzymatic and Chemical Protein Cleavage, Mass Spectrometry, Molecular Biology, Prot

相关文献及参考

  • For a review of polyvalent iodine compounds, see: Chem. Rev., 96, 1123 (1996).
  • Reagent for ɑ-hydroxylation of ketones; the by-product benzoic acid is easily removed by base extraction: Tetrahedron Lett., 25, 691 (1984). For an example, see: Org. Synth. Coll., 7, 263 (1990).
  • Catalyst for cleavage of toxic phosphates and reactive esters: Tetrahedron Lett., 28, 251 (1987); J. Am. Chem. Soc., 108, 788 (1986); 116, 4471 (1994).
  • Probably exists as the cyclized form 1-Hydroxy-1,1-dihydro-1,2-benzodioxol-3(1H)-one; CAS registry no. [161-62-4].

安全信息

RTECSDH3056550
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Light Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Hazard Codes Xi 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 196 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - rigidity (including catalepsy)
   Behavioral - muscle contraction or spasticity
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 45,289,1989

其他信息

  • F:8-23
  • 2-亚碘酰基苯甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0073 2-亚碘酰苯甲酸 2-Iodosobenzoic Acid 10G 1400元 2010/05/25 L15606 2-亚碘酰基苯甲酸, 97% 2-Iodosobenzoic acid, 97% 5g 629元 2010/05/25 L15606 2-亚碘酰基苯甲酸, 97% 2-Iodosobenzoic acid, 97% 1g 158元
  • Hazard Note:Irritant
  • Sigma Aldrich:304-91-6(sigmaaldrich)
  • 图谱信息:2-亚碘酰基苯甲酸(304-91-6)红外图谱(IR1) 2-亚碘酰基苯甲酸(304-91-6)红外图谱(IR2) 2-亚碘酰基苯甲酸(304-91-6)核磁图( 13 CNMR) 2-亚碘酰基苯甲酸(304-91-6)核磁图( 1 HNMR)
  • MOL 文件:304-91-6.mol
  • Alfa Aesar:2-亚碘酰基苯甲酸,97% 2-Iodosobenzoic acid, 97%(304-91-6)
  • TCI Shanghai:2-亚碘酰苯甲酸 2-Iodosobenzoic Acid,>;95.0%(T)(304-91-6)
  • 敏感性:Light Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Mass Spectrometry - Proteomics
  4. Enzymatic and Chemical Protein Cleavage - Mass Spectrometry
  5. Chemical Cleavage of Proteins 蛋白质剪切试剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Hypervalent Iodine Compounds

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